diphosphorus (III,V)-oic acid tetrapropyl ester

Base Information

• Chemical Name: diphosphorus (III,V)-oic acid tetrapropyl ester
• CAS No.: 690-68-6
• Molecular Formula: C₁₂H₂₈O₆P₂
• Molecular Weight: 330.298
• Mol file: 690-68-6.mol

Synonyms:diphosphorus (III,V)-oic acid tetrapropyl ester

Chemical Property of diphosphorus (III,V)-oic acid tetrapropyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of diphosphorus (III,V)-oic acid tetrapropyl ester

There total 3 articles about diphosphorus (III,V)-oic acid tetrapropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

dipropyl sodiophosphite (42414-50-6) → diphosphorus (III)-oic acid tetrapropyl ester (88351-47-7) + diphosphorus (III,V)-oic acid tetrapropyl ester (690-68-6) + diphosphoric acid tetrapropyl ester (3583-94-6) + sodium dipropyl phosphate (4545-54-4) + di-n-propyl phosphonate (1809-21-8)

Guidance literature:

With sodium perchlorate; In acetonitrile; Product distribution; Ambient temperature; object of study - electrochemical oxidation at platinum electrode;

Reference yield:

dipropyl phosphite (54722-86-0) → phosphoric acid tripropyl ester (513-08-6) + diphosphorus (III,V)-oic acid tetrapropyl ester (690-68-6) + hypophosphoric acid tetrapropyl ester (679-38-9) + diphosphoric acid tetrapropyl ester (3583-94-6)

Guidance literature:

With lithium bromide; In acetonitrile; Title compound not separated from byproducts; electrochemical oxidation, 2.4 A h; Pt anode, Ni cathode; Ag/AgNO₃ reference electrode;

Reference yield:

dipropyl phosphite (54722-86-0) → tri-n-propyl phosphite (923-99-9) + diphosphorus (III)-oic acid tetrapropyl ester (88351-47-7) + diphosphorus (III,V)-oic acid tetrapropyl ester (690-68-6) + diphosphoric acid tetrapropyl ester (3583-94-6)

Guidance literature:

With sodium perchlorate; In acetonitrile; Title compound not separated from byproducts; electrochemical oxidation, 2.4 A h; Pt anode, Ni cathode; Ag/AgNO₃ reference electrode;

upstream raw materials:

dipropyl sodiophosphite

dipropyl phosphite

Downstream raw materials:

tetrapropyl (α-cyano-α,α'-oxydibenzylidene)bisphosphonate

α-(dipropoxyphosphinyl)benzyl dipropyl phosphite

Refernces

• 1、 Romakhin, A. S.,Parakin, O. V.,Nikitin, E. V.,Ignat'ev, Yu. A.,Zagumennov, V. A.,Romanov, G. V.. "ELECTROCHEMICAL SYNTHESIS OF TETRAALKYL PYROPHOSPHITES". . p. 1960 - 1962. Retrieved 2007/10/02.