Dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer

Base Information

• Chemical Name: Dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer
• CAS No.: 96503-27-4
• Molecular Formula: C10 H15 Cl2 Ru
• Molecular Weight: 614.4
• Hs Code.: 29310099
• Mol file: 96503-27-4.mol

Synonyms:1,3-Cyclopentadiene,1,2,3,4,5-pentamethyl-, ruthenium complex, homopolymer

Chemical Property of Dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer

Chemical Property:

• Melting Point: 45-47 ºC
• PSA: 0.00000
• LogP: 4.64840
• Storage Temp.: 2-8°C
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: insoluble

Purity/Quality:

98% ^*data from raw suppliers

Dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): N
• Hazard Codes: N
• Statements: 36/37/38
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Entry points into pentamethylcyclopentadienyl chemistry of ruthenium.

Technology Process of Dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer

There total 4 articles about Dichloro(pentamethylcyclopentadienyl)ruthenium(III) polymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

1,2,3,4,5-pentamethylcyclopentadiene (4045-44-7) + ruthenium(III) chloride trihydrate → [RuCl2pentamethylcyclopentadiene]n (96503-27-4)

Guidance literature:

ruthenium(III) chloride trihydrate; In methanol; for 1h; Inert atmosphere; Schlenk technique; Reflux;

1,2,3,4,5-pentamethylcyclopentadiene; In methanol; for 6h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/acs.organomet.9b00266

Reference yield: 61.0%

ruthenium(III) chloride hydrate (20759-14-2,14898-67-0) + 1,2,3,4,5-pentamethylcyclopentadiene (4045-44-7) → pentamethylcyclopentadienylruthenium dichloride (96503-27-4)

Guidance literature:

In ethanol; 85°C, 3 h; filtration, washing with ethanol and ether, drying under reduced pressure, elem. anal.;

DOI:10.1246/cl.1984.1161

Reference yield: 56.0%

1,2,3,4,5-pentamethylcyclopentadiene (4045-44-7) + ruthenium(III)chloride (10049-08-8,63767-78-2) → bis(pentamethylcyclopentadienyl)ruthenium(II) (84821-53-4) + pentamethylcyclopentadienylruthenium dichloride (96503-27-4)

Guidance literature:

In ethanol; (N2); RuCl3 and ligand in EtOH were refluxed for 3 h, on cooling to room temp. pptd. brown solid; pptn. filtered out, washed with EtOH, ether and pentane, drying in vac. yielded main product; chromy. of the vol. reduced washings (alumina, ether) and removal of solvents afforded decamethylruthenocene;

DOI:10.1021/ja00226a030

upstream raw materials:

1,2,3,4,5-pentamethylcyclopentadiene

ruthenium(III)chloride

ruthenium(III) chloride hydrate

Downstream raw materials:

[(η5-C5Me5)RuCl(κ2-P,P-(O2C20H12)PN(CHMe2)P(OPh)2)]

trans-[Ru(H)Cl(κ2-P,P-(2,6-Me2C6H3O)2PN(Me)P(OC6H3Me2-2,6)2)(CD3CN)2]

[(η5-C5Me5)RuCl(κ2-P,P-(O2C20H12)PN(CHMe2)P(OC6H4(t-Bu)-4)2)]

[(η5-C5Me5)RuCl(κ2-P,P-(PhO)2PN(Me)P(OPh)2)]