5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)

Base Information

• Chemical Name: 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)
• CAS No.: 1039027-73-0
• Molecular Formula: C₆₀H₇₄B₂N₄O₄Zn
• Molecular Weight: 1002.28
• Mol file: 1039027-73-0.mol

Synonyms:5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)

Chemical Property of 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)

There total 4 articles about 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II) (215313-78-3) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N(21),N(22),N(23),N(24)zinc(II) (1039027-73-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; water; triethylamine; In 1,2-dichloro-ethane; for 1.5h; Inert atmosphere; Reflux;

DOI:10.1002/chem.200901502

Reference yield: 74.0%

[10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-bromoporphyrinato]zinc(II) (215313-78-3) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1039027-73-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In tetrahydrofuran; toluene; at 68 ℃; for 24h;

DOI:10.1039/c5sc01830g

Reference yield: 72.0%

[10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-bromoporphyrinato]zinc(II) (215313-78-3) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → {5,15-bis[3,5-di(tert-butyl)phenyl]-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1010693-50-1) + {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1039027-73-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In water; 1,2-dichloro-ethane; at 100 ℃; for 2h; Inert atmosphere;

DOI:10.1002/ejoc.201402634

upstream raw materials:

[5,15-dibromo-10,20-bis-(3,5-di-tert-butyphenyl)porphyrinato]zinc(II)

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

[10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-bromoporphyrinato]zinc(II)

Downstream raw materials:

5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-bromophenyl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)

C₉₆H₉₇BN₈O₂Zn₂

[5-[10-(1,8-bis(2,4,6-trimethylphenoxy)anthracene)]-10,20-bis-(3,5-di-tert-butylphenyl)-porphyrinato]zinc(II)

[5,15-[10-(1,8-bis(2,4,6-trimethylphenoxy)anthracene)]-10,20-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)