3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione

Base Information

• Chemical Name: 3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione
• CAS No.: 929893-70-9
• Molecular Formula: C₂₇H₃₆O₆
• Molecular Weight: 456.579
• Mol file: 929893-70-9.mol

Synonyms:3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione

Chemical Property of 3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione

There total 1 articles about 3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene (21988-87-4) + acetylacetone (123-54-6,81235-32-7) → 3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione (929893-70-9)

Guidance literature:

1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene; With potassium tert-butylate; In tert-butyl alcohol; Heating;

acetylacetone; With potassium iodide; In tert-butyl alcohol; for 20h; Heating;

DOI:10.1016/j.tet.2006.12.071

Reference yield: 70.0%

3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione (929893-70-9) → 1,3,5-tris-(3'-oxo-butyl)-2,4,6-trimethylbenzene (929893-73-2)

Guidance literature:

With sodium hydroxide; In methanol; water;

DOI:10.1016/j.tet.2006.12.071

Reference yield:

3-[3,5-bis-(2-acetyl-3-oxo-butyl)-2,4,6-trimethyl-benzyl]-pentane-2,4-dione (929893-70-9) → (1-methyl-3-{2,4,6-trimethyl-3,5-bis-[3-(pyridin-2-ylmethylimino)-butyl]-phenyl}-propylidene)-pyridin-2-ylmethyl-amine

Guidance literature:

Multi-step reaction with 2 steps

1: 70 percent / sodium hydroxide / methanol; H₂O

2: 96 percent / toluene / 4 h / Heating

With sodium hydroxide; In methanol; water; toluene;

DOI:10.1016/j.tet.2006.12.071

upstream raw materials:

1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene

acetylacetone

Downstream raw materials:

1,3,5-tris-(3'-oxo-butyl)-2,4,6-trimethylbenzene