[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

Base Information

Chemical Name:[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane
CAS No.:287194-57-4
Molecular Formula:C₃₅H₅₀O₄SSi
Molecular Weight:594.931
Hs Code.:

Synonyms:[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

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Chemical Property of [2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

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Technology Process of [2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

There total 15 articles about [2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 617-86-7
triethylsilane

: 287194-46-1
2-benzyloxy-6-methyl-3-phenylsulfanylethynyldodecahydro-4,8,12-trioxadibenzo[a,d]cyclooctene

: 287194-57-4
[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

Guidance literature:: In dichloromethane; at 0 ℃;

Reference yield:

: 287194-56-3
2-benzyloxy-6-methyl-3-phenylsulfanylethynyldodecahydro-4,8,12-trioxadibenzo[a,d]cyclooctene-3-ol

: 287194-57-4
[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / Et₃SiH; BF₃*OEt₂ / acetonitrile / 0.08 h / -78 °C

2: 84 percent / biscobalthexacarbonyl-2-methylbut-3-yn-2-ol / 1,2-dichloro-ethane / 0.5 h / 60 °C

With triethylsilane; boron trifluoride diethyl etherate; biscobalthexacarbonyl-2-methyl-but-3-yn-2-ol; In 1,2-dichloro-ethane; acetonitrile; 1: Reduction / 2: Reduction;
DOI:10.1016/S0040-4020(00)00467-1

Reference yield:

: 272787-63-0
2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cyclooctene-3-one

: 287194-57-4
[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / n-BuLi / tetrahydrofuran; hexane / -78 - 0 °C

2: 100 percent / Et₃SiH; BF₃*OEt₂ / acetonitrile / 0.08 h / -78 °C

3: 84 percent / biscobalthexacarbonyl-2-methylbut-3-yn-2-ol / 1,2-dichloro-ethane / 0.5 h / 60 °C

With triethylsilane; n-butyllithium; boron trifluoride diethyl etherate; biscobalthexacarbonyl-2-methyl-but-3-yn-2-ol; In tetrahydrofuran; hexane; 1,2-dichloro-ethane; acetonitrile; 1: Addition / 2: Reduction / 3: Reduction;
DOI:10.1016/S0040-4020(00)00467-1