[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

Base Information

Chemical Name:[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane
CAS No.:287194-58-5
Molecular Formula:C₃₅H₅₀O₆SSi
Molecular Weight:626.93
Hs Code.:

[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

Synonyms:[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

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Chemical Property of [(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

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Technology Process of [(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

There total 17 articles about [(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 287194-57-4
[2-(2-benzyloxy-6-methyldodecahydro-4,8,12-trioxadibenzo[a,d]cycloocten-3-yl)-1-phenylsulfanylvinyl]triethyl silane

: 287194-58-5
[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

Guidance literature:: With disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/S0040-4020(00)00467-1

Reference yield:

: 287194-46-1
2-benzyloxy-6-methyl-3-phenylsulfanylethynyldodecahydro-4,8,12-trioxadibenzo[a,d]cyclooctene

: 287194-58-5
[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / biscobalthexacarbonyl-2-methylbut-3-yn-2-ol / 1,2-dichloro-ethane / 0.5 h / 60 °C

2: 89 percent / Na₂HPO₄; mCPBA / CH₂Cl₂ / 1 h / 0 °C

With disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; biscobalthexacarbonyl-2-methyl-but-3-yn-2-ol; In dichloromethane; 1,2-dichloro-ethane; 1: Reduction / 2: Oxidation;
DOI:10.1016/S0040-4020(00)00467-1

Reference yield:

: 287194-56-3
2-benzyloxy-6-methyl-3-phenylsulfanylethynyldodecahydro-4,8,12-trioxadibenzo[a,d]cyclooctene-3-ol

: 287194-58-5
[(Z)-1-Benzenesulfonyl-2-((2S,3R,4aS,6S,7aR,11aS,12aR)-2-benzyloxy-6-methyl-dodecahydro-4,8,12-trioxa-dibenzo[a,d]cycloocten-3-yl)-vinyl]-triethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / Et₃SiH; BF₃*OEt₂ / acetonitrile / 0.08 h / -78 °C

2: 84 percent / biscobalthexacarbonyl-2-methylbut-3-yn-2-ol / 1,2-dichloro-ethane / 0.5 h / 60 °C

3: 89 percent / Na₂HPO₄; mCPBA / CH₂Cl₂ / 1 h / 0 °C

With triethylsilane; disodium hydrogenphosphate; boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; biscobalthexacarbonyl-2-methyl-but-3-yn-2-ol; In dichloromethane; 1,2-dichloro-ethane; acetonitrile; 1: Reduction / 2: Reduction / 3: Oxidation;
DOI:10.1016/S0040-4020(00)00467-1