6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

Base Information

Chemical Name:6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene
CAS No.:82911-91-9
Molecular Formula:C₁₉H₂₅NO₂
Molecular Weight:299.413
Hs Code.:

Synonyms:6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

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Chemical Property of 6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

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Technology Process of 6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

There total 22 articles about 6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 82911-90-8
3β-hydroxy-6β-formamidomethyl-8a-phenylmethyl-trans-prehydronaphthalene

: 82911-91-9
6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

Guidance literature:: With chromium(VI) oxide; In pyridine; dichloromethane; for 2h; Ambient temperature;
DOI:10.1139/v82-151

Reference yield:

: 70043-58-2
1,2,3,5,6,7,8,8a-octahydro-3-oxo-8a-phenylmethylnaphthalene

: 82911-91-9
6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

Guidance literature:: Multi-step reaction with 10 steps

1: 77 percent / p-toluenesulfonic acid monohydrate / benzene / 18 h / Heating

2: 1.) diborane, 2.) sodium hydroxide, 30percent hydrogen peroxide / 1.) tetrahydrofuran, R_.T_. 3 h, 2.) 0 degC, methanol

3: Jones reagent / acetone

4: tetrahydrofuran / 1.) 10 min., 0 degC, 2.) reflux, 20 min.

5: 1.) borane, 2.) sodium hydroxide, 30percent hydrogen peroxide / 1.) THF, R_.T_. 1.5 h, methanol, 2.) 0 degC, 15 min., sodium sulfite

6: 95 percent / pyridine / 72 h / 0 °C

7: 28 percent / sodium azide / dimethylformamide / 1 h / 125 °C

8: LAH / tetrahydrofuran / 0.5 h / Ambient temperature

9: 64 percent / conc. HCl / methanol / 1.) 30 min., 70 degC, 2.) 30 min. R_.T_.

10: sodium bicarbonate / formic acid / Heating

With hydrogenchloride; sodium hydroxide; lithium aluminium tetrahydride; sodium azide; jones reagent; borane; dihydrogen peroxide; sodium hydrogencarbonate; toluene-4-sulfonic acid; diborane; In tetrahydrofuran; pyridine; methanol; formic acid; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1139/v82-151

Reference yield:

: 946-33-8
2-benzylcyclohexan-1-one

: 82911-91-9
6β-formamidomethyl-3-oxo-8a-phenylmethyl-trans-prehydronaphthalene

Guidance literature:: Multi-step reaction with 11 steps

1: 49 percent / potassium hydroxide / diethyl ether; ethanol / 4 h / 0 °C

2: 77 percent / p-toluenesulfonic acid monohydrate / benzene / 18 h / Heating

3: 1.) diborane, 2.) sodium hydroxide, 30percent hydrogen peroxide / 1.) tetrahydrofuran, R_.T_. 3 h, 2.) 0 degC, methanol

4: Jones reagent / acetone

5: tetrahydrofuran / 1.) 10 min., 0 degC, 2.) reflux, 20 min.

6: 1.) borane, 2.) sodium hydroxide, 30percent hydrogen peroxide / 1.) THF, R_.T_. 1.5 h, methanol, 2.) 0 degC, 15 min., sodium sulfite

7: 95 percent / pyridine / 72 h / 0 °C

8: 28 percent / sodium azide / dimethylformamide / 1 h / 125 °C

9: LAH / tetrahydrofuran / 0.5 h / Ambient temperature

10: 64 percent / conc. HCl / methanol / 1.) 30 min., 70 degC, 2.) 30 min. R_.T_.

11: sodium bicarbonate / formic acid / Heating

With hydrogenchloride; potassium hydroxide; sodium hydroxide; lithium aluminium tetrahydride; sodium azide; jones reagent; borane; dihydrogen peroxide; sodium hydrogencarbonate; toluene-4-sulfonic acid; diborane; In tetrahydrofuran; pyridine; methanol; formic acid; diethyl ether; ethanol; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1139/v82-151