W(NC₆H₅)(CH₃)3Cl

Base Information

Chemical Name:W(NC₆H₅)(CH₃)3Cl
CAS No.:83634-61-1
Molecular Formula:C₉H₁₄ClNW
Molecular Weight:355.52
Hs Code.:

W(NC<sub>6</sub>H<sub>5</sub>)(CH<sub>3</sub>)3Cl

Synonyms:W(NC₆H₅)(CH₃)3Cl

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Chemical Property of W(NC₆H₅)(CH₃)3Cl

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Technology Process of W(NC₆H₅)(CH₃)3Cl

There total 1 articles about W(NC₆H₅)(CH₃)3Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 83634-27-9
[W(NC₆H₅)Cl₅]^(1-)*(N(C₂H₅)4)⁽¹⁺⁾=[W(NC₆H₅)Cl₅](N(C₂H₅)4)

: 544-97-8
dimethyl zinc(II)

: 83634-61-1
W(NC₆H₅)(CH₃)3Cl

Guidance literature:: With (C₂H₅)4NCl; In dichloromethane; pentane; W compd. and Et4NCl suspd. in CH2Cl2 under N2, mixture cooled to 0°C, Zn compd. in pentane added rapidly (1 min), suspn. stirred for 17 h; filtration, washing with toluene, evapn. in vac., extn. (Et2O), filtration, concg. in vac., cooling to -30°C, concg. mother liquor, recrystn. (Et2O, -30°C); elem. anal.;
DOI:10.1021/ja00390a016

Reference yield: 92.0%

: 83634-61-1
W(NC₆H₅)(CH₃)3Cl

: 83634-48-4
W(η5-C5H5)(NPh)(CH3)3

Guidance literature:: With cyclopentadienyl sodium; In tetrahydrofuran; NaCp added to THF soln. of W compd. under N2 at -30°C, mixture warmed to room temp., stirred for 8 h; evapn. in vac., extn. (pentane), filtration, concg. in vac., cooling to-30°C;
DOI:10.1021/ja00390a016

Reference yield: 80.0%

: 83634-61-1
W(NC₆H₅)(CH₃)3Cl

: 917-54-4
methyllithium

: 302-01-2,78206-91-4,119775-10-9,75013-58-0
hydrazine

: [W(NPh)Me3]2(μ-η1,η1-NH2NH2)(μ-η2,η2-NHNH)

Guidance literature:: In diethyl ether; byproducts: LiCl; LiCl was added to a satd. soln. of complex in ether at -30°C, transferred to a soln. of anhydrous N2H4 in ether, stirred at -30°Cfor 20 min, warmed to room temp.;; filtered, washed with ether, evapd.;;
DOI:10.1021/ja00338a064