Carbon monoxide;3-diphenylphosphaniumylpropyl(diphenyl)phosphanium;tungsten

Base Information

Chemical Name:Carbon monoxide;3-diphenylphosphaniumylpropyl(diphenyl)phosphanium;tungsten
CAS No.:50860-43-0
Molecular Formula:C₃₁H₂₆O₄P₂W
Molecular Weight:708.343
Hs Code.:
DSSTox Substance ID:DTXSID30422998

Synonyms:NSC193744;50860-43-0;DTXSID30422998

Suppliers and Price of Carbon monoxide;3-diphenylphosphaniumylpropyl(diphenyl)phosphanium;tungsten

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Carbon monoxide;3-diphenylphosphaniumylpropyl(diphenyl)phosphanium;tungsten

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:710.097217
Heavy Atom Count:38
Complexity:360

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[PH+](CCC[PH+](C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[W]

Technology Process of Carbon monoxide;3-diphenylphosphaniumylpropyl(diphenyl)phosphanium;tungsten

There total 5 articles about Carbon monoxide;3-diphenylphosphaniumylpropyl(diphenyl)phosphanium;tungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 14040-11-0
tungsten hexacarbonyl

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 50860-43-0
tetracarbonyl-1,3-bis(diphenylphosphino)propane-tungsten⁽⁰⁾

Guidance literature:: With sodium tetrahydroborate; at 120 ℃; for 0.666667h; under 760.051 Torr; Microwave irradiation; Inert atmosphere; Green chemistry;
DOI:10.1016/j.inoche.2012.09.030

Reference yield: 94.0%

: 14040-11-0,199620-16-1
tungsten hexacarbonyl

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 50860-43-0
C₃₁H₂₆O₄P₂W

Guidance literature:: With sodium tetrahydroborate; at 120 ℃; for 0.666667h; under 760.051 Torr; Microwave irradiation; Inert atmosphere; Green chemistry;
DOI:10.1016/j.inoche.2012.09.030

Reference yield: 78.0%

: 15096-68-1
pentacarbonyl(acetonitrile)tungsten

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 50860-43-0
tetracarbonyl-1,3-bis(diphenylphosphino)propane-tungsten⁽⁰⁾

: 113803-77-3
1,3-bis(diphenylphosphino)propanetungsten decacarbonyl

Guidance literature:: In toluene; (W(CO)5(NCMe)) and diphosphine (molar ratio: 2:1) refluxed in toluene under nitrogen (2-2.5 h), soln. filtered through cellulose, pumped to dryness; washing with hexane or chromy. (silica gel, benzene); 31P-NMR;
DOI:10.1016/S0020-1693(00)80834-8