4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde

Base Information

• Chemical Name: 4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde
• CAS No.: 119770-81-9
• Molecular Formula: C₄₈H₃₆N₄O
• Molecular Weight: 684.84
• Mol file: 119770-81-9.mol

Synonyms:4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde

Chemical Property of 4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde

There total 4 articles about 4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

5-(4-hydroxymethylphenyl)-10,15,20-tris(4-methylphenyl)porphyrin (121869-50-9) → 5-(4'-formylphenyl)-10,15,20-tri(4''-methylphenyl)porphyrin (119770-81-9)

Guidance literature:

With manganese(IV) oxide; In dichloromethane;

DOI:10.1142/S1088424616501248

Reference yield:

pyrrole (109-97-7,30604-81-0) + 4-methyl-benzaldehyde (104-87-0) + 4-bromo-benzaldehyde (1122-91-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → C48H34N4O2 + 4-((5Z,10Z,14Z,19Z)-10,15,20-Tri-p-tolyl-porphyrin-5-yl)-benzaldehyde (119770-81-9)

Guidance literature:

pyrrole; 4-methyl-benzaldehyde; 4-bromo-benzaldehyde; In propionic acid; for 0.75h; Reflux;

N,N-dimethyl-formamide; With n-butyllithium; In propionic acid;

DOI:10.1021/ja9057713

Reference yield:

4-methyl-benzaldehyde (104-87-0) → 5-(4'-formylphenyl)-10,15,20-tri(4''-methylphenyl)porphyrin (119770-81-9)

Guidance literature:

Multi-step reaction with 3 steps

1: propionic acid / 1 h / Reflux

2: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 0 - 20 °C

3: manganese(IV) oxide / dichloromethane

With manganese(IV) oxide; lithium aluminium tetrahydride; propionic acid; In tetrahydrofuran; dichloromethane;

DOI:10.1142/S1088424616501248

upstream raw materials:

4-methyl-benzaldehyde

5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin

5-(4-hydroxymethylphenyl)-10,15,20-tris(4-methylphenyl)porphyrin

pyrrole

Downstream raw materials:

C₅₁H₃₅N₅O₂Zn

{5-(4'-formylphenyl)-10,15,20-tri(4''-tolyl)porphyrinato}zinc(II)