5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin

Base Information

• Chemical Name: 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin
• CAS No.: 57105-80-3
• Molecular Formula: C₄₉H₃₈N₄O₂
• Molecular Weight: 714.866
• Mol file: 57105-80-3.mol

Synonyms:5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin

Chemical Property of 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin

There total 7 articles about 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

4-methyl-benzaldehyde (104-87-0) + 5-(4-methylphenyl)dipyrromethane (147804-55-5) + methyl 4-formylbenzoate (1571-08-0) → 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (57105-80-3)

Guidance literature:

4-methyl-benzaldehyde; 5-(4-methylphenyl)dipyrromethane; methyl 4-formylbenzoate; With boron trifluoride diethyl etherate; In chloroform; at 20 ℃; for 1.33333h;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; at 20 ℃; for 1h;

DOI:10.1039/a907428g

Reference yield: 15.0%

pyrrole (109-97-7,30604-81-0) + p-Anisaldehyde dimethyl acetal (2186-92-7) + 4-methyl-benzaldehyde (104-87-0) → H2-5,15-di(p-methoxycarbonylphenyl)-10,20-di(p-tolyl)porphyrin (57056-44-7) + 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (57105-80-3) + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) + 5,10-bis(4-methoxycarbonylphenyl)-15,20-bis(4-methylphenyl)porphyrin

Guidance literature:

With propionic acid; 1.) reflux, 1 h, 2.) 5 deg C, 24 h;

DOI:10.1016/S0040-4020(01)86323-7

Reference yield: 6.2%

pyrrole (109-97-7,30604-81-0) + 4-methyl-benzaldehyde (104-87-0) + methyl 4-formylbenzoate (1571-08-0) → 5,10,15-tris(4-methylphenyl)-20-(4-methoxycarbonylphenyl)porphyrin (57105-80-3)

Guidance literature:

With propionic acid; for 1h; Reflux;

DOI:10.1142/S1088424616501248

upstream raw materials:

pyrrole

p-Anisaldehyde dimethyl acetal

4-methyl-benzaldehyde

methyl 4-formylbenzoate

Downstream raw materials:

5-(4-hydroxymethylphenyl)-10,15,20-tris(4-methylphenyl)porphyrin

5-(4'-formylphenyl)-10,15,20-tri(4''-methylphenyl)porphyrin

5-(4-bromomethylphenyl)-10,15,20-tri-p-tolylporphyrin