Glycerol triglycidyl ether

Base Information

• Chemical Name: Glycerol triglycidyl ether
• CAS No.: 13236-02-7
• Deprecated CAS: 161257-16-5
• Molecular Formula: C12H20 O6
• Molecular Weight: 260.287
• Hs Code.: 2910900090
• European Community (EC) Number: 236-211-1
• UNII: 0KVT2Q7Z17
• DSSTox Substance ID: DTXSID00884584
• Nikkaji Number: J213.768B
• Wikidata: Q27236908
• Mol file: 13236-02-7.mol

Synonyms:glycerol 1,2,3-triglycidyl ether

Chemical Property of Glycerol triglycidyl ether

Chemical Property:

• Vapor Pressure: 1.35E-05mmHg at 25°C
• Boiling Point: 378.7oC at 760 mmHg
• Flash Point: 158.7oC
• PSA: 65.28000
• Density: 1.251g/cm3
• LogP: -0.39880
• XLogP3: -1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 11
• Exact Mass: 260.12598835
• Heavy Atom Count: 18
• Complexity: 243

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> Glycidyl Ethers
• Canonical SMILES: C1C(O1)COCC(COCC2CO2)OCC3CO3
• Description: Glycerol triglycidyl ether is colorless to slight yellow transparent liquid.Glycerol triglycidyl ether is used in paint and coating applications such as appliance paint, boat paint, building coating, car paint, electrical insulating varnish, furniture paint, paper coating, plastic coating, road marking paint, rubber coating.

Technology Process of Glycerol triglycidyl ether

There total 4 articles about Glycerol triglycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1,2,3-tri-O-allylglycerol (2565-21-1) → glycidyl ether of glycerine (13236-02-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;

DOI:10.1039/c5ra25267a

Reference yield:

C12H23Cl3O6 (50794-09-7) → glycidyl ether of glycerine (13236-02-7)

Guidance literature:

With sodium hydroxide; at 80 ℃; for 1.33333h;

Reference yield:

glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → glycidyl ether of glycerine (13236-02-7)

Guidance literature:

With sodium hydroxide; In water; at 50 ℃; for 8h;

DOI:10.1007/s11743-010-1213-8

upstream raw materials:

1,2,3-tri-O-allylglycerol

glycerol

epichlorohydrin

C₁₂H₂₃Cl₃O₆

Downstream raw materials:

C₅₁H₅₀O₁₂

Refernces

• 1、 Xu, Hujun,Chen, Dandan,Cui, Zhenggang. "Study on the synthesis and surface active properties of a novel surfactant with triple quaternary ammonium groups and triple dodecyl chains derived from glycerin". . p. 167 - 172. Retrieved 2011.
• 2、 -. "A coating of anti-agent and its preparation method and application". Paragraph 0028; 0029. . Retrieved 2017/05/12.