2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Base Information

Chemical Name:2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol
CAS No.:136459-85-3
Molecular Formula:C₃₂H₃₆O₇
Molecular Weight:532.634
Hs Code.:

Synonyms:2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Suppliers and Price of 2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

There total 8 articles about 2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 87937-85-7
2-Benzyloxy-2-methyl-pent-4-enal

: 136459-79-5
Trimethyl-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-stannane

: 136459-85-3
2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Guidance literature:: With methyllithium; In hexane; toluene; addn. of CH3Li in hexane to the stannane in toluene at -78°C, warming to -15°C during 30 min, addn. of the aldehyde in toluene; after 10 min the reaction was quenched with pH 7 phosphate buffer, mixture was extd. with Et2O (3x), washed with brine, dried (Na2SO4), filtered, removal of solvent in vac., purification by PTLC (hexane/Et2O = 1/1);
DOI:10.1021/ja00018a041

Reference yield:

: 52869-21-3
1-hydroxy-5-methoxy-9,10-anthraquinone

: 136459-85-3
2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / (i-Pr)2NEt / CH₂Cl₂ / Ambient temperature

2: H₂ / 10percent Pd/C / dimethylformamide / 0.25 h / 760 Torr / Ambient temperature

3: 1.) NaH / 1.) DMF, RT, 15 min, 2.) DMF, RT, 20 min

With hydrogen; sodium hydride; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00018a041

Reference yield:

: 121564-53-2
1-(methoxymethoxy)-5-methoxy-9,10-anthraquinone

: 136459-85-3
2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: H₂ / 10percent Pd/C / dimethylformamide / 0.25 h / 760 Torr / Ambient temperature

2: 1.) NaH / 1.) DMF, RT, 15 min, 2.) DMF, RT, 20 min

With hydrogen; sodium hydride; palladium on activated charcoal; In N,N-dimethyl-formamide;
DOI:10.1021/ja00018a041