2-(Benzyloxy)-2-methylpent-4-enal

Base Information

Chemical Name:2-(Benzyloxy)-2-methylpent-4-enal
CAS No.:87937-85-7
Molecular Formula:C13H16O2
Molecular Weight:204.269
Hs Code.:
DSSTox Substance ID:DTXSID90527059

Synonyms:2-(Benzyloxy)-2-methylpent-4-enal;87937-85-7;DTXSID90527059

Suppliers and Price of 2-(Benzyloxy)-2-methylpent-4-enal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(Benzyloxy)-2-methylpent-4-enal

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:204.115029749
Heavy Atom Count:15
Complexity:207

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(CC=C)(C=O)OCC1=CC=CC=C1

Technology Process of 2-(Benzyloxy)-2-methylpent-4-enal

There total 1 articles about 2-(Benzyloxy)-2-methylpent-4-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.7%

: 128549-25-7
2-Benzyloxy-2-methyl-pent-4-en-1-ol

: 87937-85-7
2-Benzyloxy-2-methyl-pent-4-enal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 0.166667h;
DOI:10.1021/ja00018a041

Reference yield: 88.0%

: 136459-78-4
C₁₄H₆(OCH₃)2(OCH₂OCH₃)(Sn(CH₃)3)

: 87937-85-7
2-Benzyloxy-2-methyl-pent-4-enal

: 136459-84-2
2-Benzyloxy-1-(9,10-dimethoxy-1-methoxymethoxy-anthracen-2-yl)-2-methyl-pent-4-en-1-ol

Guidance literature:: With n-butyllithium; In hexane; toluene; addn. of n-BuLi in hexane to the stannane in toluene at -78°C, warming to -15°C during 30 min, addn. of the aldehyde in toluene; after 10 min the reaction was quenched with pH 7 phosphate buffer, mixture was extd. with Et2O (3x), washed with brine, dried (Na2SO4), filtered, removal of solvent in vac., purification by PTLC (hexane/Et2O = 1/1);
DOI:10.1021/ja00018a041

Reference yield: 77.0%

: 87937-85-7
2-Benzyloxy-2-methyl-pent-4-enal

: 136459-79-5
Trimethyl-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-stannane

: 136459-85-3
2-Benzyloxy-2-methyl-1-(5,9,10-trimethoxy-1-methoxymethoxy-anthracen-2-yl)-pent-4-en-1-ol

Guidance literature:: With methyllithium; In hexane; toluene; addn. of CH3Li in hexane to the stannane in toluene at -78°C, warming to -15°C during 30 min, addn. of the aldehyde in toluene; after 10 min the reaction was quenched with pH 7 phosphate buffer, mixture was extd. with Et2O (3x), washed with brine, dried (Na2SO4), filtered, removal of solvent in vac., purification by PTLC (hexane/Et2O = 1/1);
DOI:10.1021/ja00018a041