methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate

Base Information

Chemical Name:methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate
CAS No.:80594-22-5
Molecular Formula:C₁₁H₁₂O₂
Molecular Weight:179.191
Hs Code.:

Synonyms:methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate

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Chemical Property of methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate

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Technology Process of methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate

There total 3 articles about methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 52751-11-8
cis<α,β-2H2>styrene

: 80594-22-5
methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) (+)-(R)-2-<2,2-bis(5-tert-butyl-2-heptylphenyl)-2-hydroxy-1-methylethylimino>methylphenolcopper complex, 2.) aq. sodium hydroxide, methanol / 1.) cyclohexane, 75 deg C, 9 h, 2.) reflux, 20 h

With methanol; sodium hydroxide; (+)-(R)-2-<2,2-bis(5-tert-butyl-2-heptylphenyl)-2-hydroxy-1-methylethylimino>methylphenolcopper;
DOI:10.1021/ja00369a036

Reference yield:

: 536-74-3
phenylacetylene

: 80594-22-5
methyl (+)-(1S,2S,3S)-t-2-phenyl-1,2,c-3-trideuteriocyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) triphenyltin deuteride, 2.) n-butyllithium, O-deuterioethanol / 1.) 5 min, 2.) THF, hexane, -78 deg C

2: 1.) (+)-(R)-2-<2,2-bis(5-tert-butyl-2-heptylphenyl)-2-hydroxy-1-methylethylimino>methylphenolcopper complex, 2.) aq. sodium hydroxide, methanol / 1.) cyclohexane, 75 deg C, 9 h, 2.) reflux, 20 h

With methanol; sodium hydroxide; n-butyllithium; ethyl [2]alcohol; (+)-(R)-2-<2,2-bis(5-tert-butyl-2-heptylphenyl)-2-hydroxy-1-methylethylimino>methylphenolcopper; triphenylstannane-d₁;
DOI:10.1021/ja00369a036