1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

Base Information

Chemical Name:1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene
CAS No.:1228259-50-4
Molecular Formula:C₂₈H₁₉BrF₂₆
Molecular Weight:929.321
Hs Code.:

Synonyms:1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

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Chemical Property of 1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

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Technology Process of 1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

There total 3 articles about 1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 1228259-49-1
9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-yne

: 699119-05-6
1-bromo-4-iodo-2,5-dimethylbenzene

: 1318254-95-3
9-(4-bromophenyl)-2,6-dichloro-9H-purine

: 1228259-50-4
1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / 30 h / 20 °C / Inert atmosphere

2: bis-triphenylphosphine-palladium(II) chloride; caesium carbonate / ethanol; toluene / 24 h / 73 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; caesium carbonate; diisopropylamine; In ethanol; toluene; 1: Sonogashira coupling / 2: Suzuki coupling;
DOI:10.1021/ic201092s

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 1228259-49-1
9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-yne

: 699119-05-6
1-bromo-4-iodo-2,5-dimethylbenzene

: 1318254-95-3
9-(4-bromophenyl)-2,6-dichloro-9H-purine

: 1228259-50-4
1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

: C₁₉H₂₉Br

: 1231971-84-8
2-(4-bromophenyl)-1-tridecene

Guidance literature:: 1,4-bromoiodobenzene; 3,6-di-methoxy-9H-carbazole; With copper(ll) sulfate pentahydrate; potassium carbonate; at 126.84 ℃; for 18h; Inert atmosphere; Neat (no solvent);

trimethylsilylacetylene; With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 59.84 ℃; for 4h; Inert atmosphere;
DOI:10.1002/chem.201200794

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 1228259-49-1
9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-yne

: 114091-36-0
tributyl(trimethylgermyl)stannane

: 699119-05-6
1-bromo-4-iodo-2,5-dimethylbenzene

: 1318254-95-3
9-(4-bromophenyl)-2,6-dichloro-9H-purine

: 1228259-50-4
1-bromo-4-[9,9,10,10,11,11,12,12,13,13,14,14,14-tridecafluoro-6-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)tetradec-1-ynyl]benzene

: C₁₉H₂₉Br

: 1231971-84-8
2-(4-bromophenyl)-1-tridecene

: (C₆H₁₁)CHC(C₆H₄Br)CH₂Ge(CH₃)3

: 644994-78-5
(C₆H₁₁)CHC(C₆H₄Br)CH₂Ge(CH₃)3

Guidance literature:: 1,4-bromoiodobenzene; 3,6-di-methoxy-9H-carbazole; With copper(ll) sulfate pentahydrate; potassium carbonate; at 126.84 ℃; for 18h; Inert atmosphere; Neat (no solvent);

trimethylsilylacetylene; With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 59.84 ℃; for 4h; Inert atmosphere;
DOI:10.1002/chem.201200794