Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

Base Information

Chemical Name:Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane
CAS No.:741271-30-7
Molecular Formula:C₂₀H₂₈O₂Si
Molecular Weight:328.527
Hs Code.:

Synonyms:Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

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Chemical Property of Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

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Technology Process of Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

There total 1 articles about Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 36551-06-1
3-(tetrahydropyran-2-yloxy)-1-trimethylsilylprop-1-yne

: 4392-24-9
Cinnamyl bromide

: 741271-30-7
Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

Guidance literature:: 3-(tetrahydropyran-2-yloxy)-1-trimethylsilylprop-1-yne; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 1h;

Cinnamyl bromide; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 2h;
DOI:10.1021/ja0474695

Reference yield:

: 741271-30-7
Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

: 741271-32-9
(E)-6-Phenyl-1-trimethylsilanyl-hex-5-en-1-yn-3-ol

Guidance literature:: With 8-aminopyrene-1,3,6-trisulfonic acid, trisodium salt; In methanol; at 20 ℃; for 3h;
DOI:10.1021/ja0474695

Reference yield:

: 741271-30-7
Trimethyl-[(E)-6-phenyl-3-(tetrahydro-pyran-2-yloxy)-hex-5-en-1-ynyl]-silane

: 741271-18-1
(E)-6-phenylhex-5-en-1-yn-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1: PTSA / methanol / 20 °C

2: KF; H₂O / dimethylsulfoxide / 20 °C

With potassium fluoride; water; toluene-4-sulfonic acid; In methanol; dimethyl sulfoxide;
DOI:10.1055/s-2007-983736