(S)-S-tert-butyl 2-methylpropane-2-sulfinothioate

Base Information

Chemical Name:(S)-S-tert-butyl 2-methylpropane-2-sulfinothioate
CAS No.:60011-16-7
Molecular Formula:C8H18OS2
Molecular Weight:194.362
Hs Code.:2930909090
European Community (EC) Number:633-129-1
Mol file:60011-16-7.mol

Synonyms:60011-16-7;(S)-S-tert-butyl 2-methylpropane-2-sulfinothioate;(S)-(-)-tert-Butyl tert-butanethiosulfinate;2-methyl-2-{[(S)-2-methylpropane-2-sulfinyl]sulfanyl}propane;2-[(S)-tert-butylsulfinyl]sulfanyl-2-methylpropane;C8H18OS2;2-Propanesulfinothioic acid, 2-methyl-, S-(1,1-dimethylethyl) ester, (S)-;SCHEMBL14919006;ZFKIFCIQBZYNIQ-NSHDSACASA-N;MFCD09028107;AKOS015841450;AKOS015963124;DS-18071;CS-0154653;A11400;(S)-s-t-Butyl 2-methylpropane-2-sulfinothioate;2-[[(S)-tert-butylsulfinyl]thio]-2-methylpropane;A832570;2-[(S)-tert-butylsulfanylsulfinyl]-2-methyl-propane;2-[(S)-tert-butylsulfinyl]sulfanyl-2-methyl-propane

Suppliers and Price of (S)-S-tert-butyl 2-methylpropane-2-sulfinothioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
(S)-S-tert-Butyl 2-methylpropane-2-sulfinothioate 95+%
5g
$ 1071.00

Matrix Scientific
(S)-S-tert-Butyl 2-methylpropane-2-sulfinothioate 95+%
250mg
$ 167.00

Matrix Scientific
(S)-S-tert-Butyl 2-methylpropane-2-sulfinothioate 95+%
1g
$ 370.00

Apolloscientific
(S)-tert-Butanethiosulfinate 95%
250mg
$ 269.00

Apolloscientific
(S)-tert-Butanethiosulfinate 95%
1g
$ 805.00

American Custom Chemicals Corporation
(S)-TERT-BUTANETHIOSULFINATE 95.00%
100G
$ 4547.81

American Custom Chemicals Corporation
(S)-TERT-BUTANETHIOSULFINATE 95.00%
25G
$ 2122.31

American Custom Chemicals Corporation
(S)-TERT-BUTANETHIOSULFINATE 95.00%
5G
$ 1249.13

Ambeed
(S)-S-tert-Butyl2-methylpropane-2-sulfinothioate 98%
5g
$ 380.00

Ambeed
(S)-S-tert-Butyl2-methylpropane-2-sulfinothioate 98%
1g
$ 108.00

Total 22 raw suppliers

Chemical Property of (S)-S-tert-butyl 2-methylpropane-2-sulfinothioate

Chemical Property:

Refractive Index:1.542
Boiling Point:209.3 °C at 760 mmHg
Flash Point:80.4 °C
PSA：75.08000
Density:1.055±0.06 g/cm3(Predicted)
LogP:2.24410
Storage Temp.:Sealed in dry,Room Temperature
XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:194.07990754
Heavy Atom Count:11
Complexity:151

Purity/Quality:

99%, ^*data from raw suppliers

(S)-S-tert-Butyl 2-methylpropane-2-sulfinothioate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)SS(=O)C(C)(C)C
Isomeric SMILES:CC(C)(C)S[S@](=O)C(C)(C)C
General Description (S)-tert-Butanethiosulfinate is an important chiral synthon that has been successfully resolved with high enantioselectivity (>99% ee) through molecular complexation with (R)-BINOL, driven primarily by hydrogen bonding interactions. It can also be synthesized via enantioselective oxidation of di-tert-butyl disulfide using vanadium catalysts and chiral ligands, though the mechanism involves competing pathways that influence enantioselectivity. (S)-tert-Butanethiosulfinate serves as a versatile intermediate in asymmetric synthesis.

Technology Process of (S)-S-tert-butyl 2-methylpropane-2-sulfinothioate

There total 3 articles about (S)-S-tert-butyl 2-methylpropane-2-sulfinothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 110-06-5
di-tert-butyl disulfide

: 60011-16-7
(_S_S)-(+)-tert-butyl tert-butanethiosulfinate

Guidance literature:: With bis(acetylacetonate)oxovanadium; C₂₇H₃₉NO₂Si; dihydrogen peroxide; In acetone; at -5 - 0 ℃;

Reference yield:

: 110-06-5
di-tert-butyl disulfide

: 67734-35-4
(R)-tert-butyl tert-butanethiosulfinate

: 60011-16-7
(_S_S)-(+)-tert-butyl tert-butanethiosulfinate

Guidance literature:: With (S,S)-(-)-2-(d-10-camphorsulfonyl)-3-(2-chloro-5-nitrophenyl)oxaziridine; In chloroform; at 25 ℃; Product distribution;
DOI:10.1021/ja00384a028