IrBr(cod)(PPh₃)

Base Information

Chemical Name:IrBr(cod)(PPh₃)
CAS No.:59980-26-6
Molecular Formula:C₂₆H₂₇BrIrP
Molecular Weight:642.598
Hs Code.:

Synonyms:IrBr(cod)(PPh₃)

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Chemical Property of IrBr(cod)(PPh₃)

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Technology Process of IrBr(cod)(PPh₃)

There total 4 articles about IrBr(cod)(PPh₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 89232-37-1
η2-(η4-cyclooctadiene)(η2-bromophenyl(diphenylphosphine))iridium(I) hexafluoroantimonate

: 59980-26-6
IrBr(cod)(PPh₃)

Guidance literature:: With sodium formate; In dichloromethane; {Ir(cod)(η2-o-BrC6H4PPh2)}SbF6 and sodium formate are stirred in CH2Cl2 at 25°C for 44 h.; filtration through Celite, evapn. to reduced volume, addn. of heptane, pptn., filtration, washing with heptane, drying in vacuo, identified by NMR- and IR-spectra;
DOI:10.1016/0022-328X(88)89103-4

Reference yield:

: 89232-36-0
C₂₆H₂₆BrIrP⁽¹⁺⁾

: 59980-26-6
(C₈H₁₂)Ir(P(C₆H₅)3)Br

Guidance literature:: With LiBEt₃H; In tetrahydrofuran; 25°C, 2 h, inert atmosphere;
DOI:10.1021/om00153a035

Reference yield:

: 89232-35-9
{Ir(cod)Cl(μ1-o-C6H4(Br)PPh2)}

: 59980-26-6
IrBr(cod)(PPh₃)

Guidance literature:: With LiBEt₃H; In tetrahydrofuran; reaction of {IrCl(cod)(η1-o-BrC6H4PPh2)} with LiBEt3H (1 M soln. in THF) at -80°C;
DOI:10.1016/0022-328X(88)89103-4