tris(tri-o-tolylphosphite)nickel⁽⁰⁾

Base Information

• Chemical Name: tris(tri-o-tolylphosphite)nickel⁽⁰⁾
• CAS No.: 28829-00-7
• Molecular Formula: C₆₃H₆₃NiO₉P₃
• Molecular Weight: 1115.8
• Mol file: 28829-00-7.mol

Synonyms:tris(tri-o-tolylphosphite)nickel⁽⁰⁾

Chemical Property of tris(tri-o-tolylphosphite)nickel⁽⁰⁾

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of tris(tri-o-tolylphosphite)nickel⁽⁰⁾

There total 2 articles about tris(tri-o-tolylphosphite)nickel⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

bis(2,4-pentanedionato)-nickel(II) + tri(O-methylphenyl)phosphite (2622-08-4) → tris(tri-o-tolylphosphite)nickel(0) (28829-00-7)

Guidance literature:

With triethylaluminum; In hexane; toluene; to cold ( 0 °C) soln. of Ni complex and phosphite in toluene added over 20 min soln. of AlEt3 in hexane, heated to 65 °C for 1 h while maintaining strong N2 purge; concd., added cold petroleum ether, soln. cold to -25 °C, filtered, ppt. dissolved in hot (75 °C) toluene, pptd. by cold MeOH, dried in vac.;

DOI:10.1021/om50004a024

Reference yield:

Ni[P[(O-o-tolyl)]3]4 (36841-11-9) → tris(tri-o-tolylphosphite)nickel(0) (28829-00-7) + tri(O-methylphenyl)phosphite (2622-08-4)

Guidance literature:

In ⁽²⁾H₈-toluene; room temp.;; not sepd., detected by NMR spectra;; Kinetics;

DOI:10.1021/ja00277a022

Reference yield: 67.0%

tris(tri-o-tolylphosphite)nickel(0) (28829-00-7) + 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene (173035-11-5) → Ni(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)[P(O-o-tol)3]2

Guidance literature:

In toluene; at 100 ℃; for 0.25h; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.organomet.9b00672

upstream raw materials:

tri(O-methylphenyl)phosphite

Ni[P[(O-o-tolyl)]₃]₄

Downstream raw materials:

C₂H₃ClNi(P(OC₆H₄CH₃-o)3)2

CHFCF₂Ni(P(OC₆H₄CH₃-o)3)2

CH₂CHOOCCH₃Ni(P(OC₆H₄CH₃-o)3)2

C₆H₉CHCH₂Ni(P(OC₆H₄CH₃-o)3)2