(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

Base Information

Chemical Name:(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate
CAS No.:1582229-87-5
Molecular Formula:C₂₀H₂₅NO₃S
Molecular Weight:359.489
Hs Code.:

Synonyms:(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

Chemical Property:

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Technology Process of (2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

There total 1 articles about (2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-52-7
benzaldehyde

: (Rs)-N-tert-butylsulfinyl-2-phenylethanimidate

: 1582229-87-5
(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

: 1582229-88-6
(2R,3R)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropanimidate

Guidance literature:: With titanium(IV) dichlorodiisopropylate; triethylamine; In dichloromethane; at 20 ℃; for 18h; Reagent/catalyst; Concentration; Solvent; Time; Temperature; Overall yield = 90 %; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ol500520h

Reference yield:

: 1582229-87-5
(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

: 100-52-7
benzaldehyde

: (Rs)-N-tert-butylsulfinyl-2-phenylethanimidate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane;
DOI:10.1021/ol500520h

Reference yield:

: 1582229-87-5
(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2,3-diphenylpropan-imidate

: 1582230-08-7
(2R,3S)-methyl N-((R)-tert-butylsulfinyl)-3-hydroxy-2-phenyl-3-(o-tolyl)-propanimidate

Guidance literature:: Multi-step reaction with 2 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane

2: triethylamine; titanium(IV) dichlorodiisopropylate / dichloromethane / 20 °C / Inert atmosphere

With titanium(IV) dichlorodiisopropylate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In dichloromethane;
DOI:10.1021/ol500520h