2-phenyl-9-p-tolylanthracene

Base Information

• Chemical Name: 2-phenyl-9-p-tolylanthracene
• CAS No.: 1401613-32-8
• Molecular Formula: C₂₇H₂₀
• Molecular Weight: 344.456
• Mol file: 1401613-32-8.mol

Synonyms:2-phenyl-9-p-tolylanthracene

Chemical Property of 2-phenyl-9-p-tolylanthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-phenyl-9-p-tolylanthracene

There total 5 articles about 2-phenyl-9-p-tolylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C37H40O4 (1401613-73-7) → 2-phenyl-9-p-tolylanthracene (1401613-32-8)

Guidance literature:

With zinc dibromide; In dichloromethane; for 0.333333h; Inert atmosphere;

DOI:10.1021/jo301410w

Reference yield:

C27H22O → 2-phenyl-9-p-tolylanthracene (1401613-32-8)

Guidance literature:

Multi-step reaction with 4 steps

1: lead(IV) tetraacetate / tetrahydrofuran / 0.5 h / 50 °C

2: sodium tetrahydroborate / tetrahydrofuran; ethanol / 4 h / Reflux

3: triethylamine; dmap / dichloromethane / 0.5 h / Inert atmosphere; Reflux

4: zinc dibromide / dichloromethane / 0.33 h / Inert atmosphere

With dmap; sodium tetrahydroborate; lead(IV) tetraacetate; triethylamine; zinc dibromide; In tetrahydrofuran; ethanol; dichloromethane;

DOI:10.1021/jo301410w

Reference yield:

para-bromotoluene (106-38-7) → 2-phenyl-9-p-tolylanthracene (1401613-32-8)

Guidance literature:

Multi-step reaction with 5 steps

1: magnesium

2: lead(IV) tetraacetate / tetrahydrofuran / 0.5 h / 50 °C

3: sodium tetrahydroborate / tetrahydrofuran; ethanol / 4 h / Reflux

4: triethylamine; dmap / dichloromethane / 0.5 h / Inert atmosphere; Reflux

5: zinc dibromide / dichloromethane / 0.33 h / Inert atmosphere

With dmap; sodium tetrahydroborate; lead(IV) tetraacetate; magnesium; triethylamine; zinc dibromide; In tetrahydrofuran; ethanol; dichloromethane;

DOI:10.1021/jo301410w

upstream raw materials:

biphenyl-4-yl(2-(4-methylbenzoyl)phenyl)methanone

C₃₇H₄₀O₄

para-bromotoluene