(E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

Base Information

Chemical Name:(E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane
CAS No.:1435479-20-1
Molecular Formula:C₂₈H₄₁BO₃Si
Molecular Weight:464.528
Hs Code.:

Synonyms:(E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

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Chemical Property of (E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

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Technology Process of (E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

There total 3 articles about (E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 128217-23-2
1-(tert-butyldiphenylsilyloxy)-5-hexyne

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1435478-83-3
(Z)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

: 1435479-20-1
(E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

Guidance literature:: With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triethylamine; tricyclohexylphosphine; In cyclohexane; at 20 ℃; for 4h; Overall yield = 62 %; Overall yield = 110 mg;
DOI:10.1039/c3ob40131f

Reference yield:

: 76-09-5
2,3-dimethyl-2,3-butane diol

: C₂₉H₃₈BBr₂NOSi

: 1435479-20-1
(E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/acs.orglett.8b00335

Reference yield:

: 185999-07-9
tert-butyl(hex-5-enyloxy)diphenylsilane

: 1435479-20-1
(E)-tert-butyldiphenyl((6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hex-5-en-1-yl)oxy)silane

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane / 24 h / 0 °C / Inert atmosphere

2: N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / 20 °C / Inert atmosphere

With N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1021/acs.orglett.8b00335