1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Base Information

Chemical Name:1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester
CAS No.:141292-99-1
Molecular Formula:C₂₉H₄₄O₆Si
Molecular Weight:516.75
Hs Code.:

1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Synonyms:1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Suppliers and Price of 1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

There total 16 articles about 1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 141292-98-0
1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid

: 141292-99-1
1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:: DOI:10.1021/jo00037a005

Reference yield:

: 40665-79-0
(3-benzyloxy-2-oxopropyl)phosphonic acid dimethyl ester

: 141292-99-1
1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 15 steps

1: 75 percent / K₂CO₃, 18-crown-6 / acetonitrile

2: 86 percent / DMPU / tetrahydrofuran

3: 91 percent / TBAF

4: 100 percent / DMSO

5: 83 percent / CH₂Cl₂

6: 95 percent / DIBAH

7: 93 percent / imidazole

8: 88 percent / chiral N-tosyl-4-methylindol-3-yl-oxazaborolidin-3-one / CH₂Cl₂ / 8 h / -78 - -40 °C

9: 99 percent / NaBH₄ / methanol

10: 98 percent / NaOMe / methanol / 5 h / Ambient temperature

11: 96 percent / NaOH / 2-methyl-propan-2-ol

12: MCPBA / CH₂Cl₂

13: 90 percent / NaOAC / 125 °C

14: 90 percent / NaClO₂ / 2-methyl-propan-2-ol; H₂O

15: 100 percent

With 1H-imidazole; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; sodium hydroxide; sodium chlorite; sodium tetrahydroborate; 18-crown-6 ether; tetrabutyl ammonium fluoride; sodium methylate; sodium acetate; diisobutylaluminium hydride; potassium carbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; chiral N-tosyl-4-methylindol-3-yl-oxazaborolidin-3-one; In tetrahydrofuran; methanol; dichloromethane; water; acetonitrile; tert-butyl alcohol;
DOI:10.1021/jo00037a005

Reference yield:

: 141292-86-6
(2E,4Z)-4-Benzyloxymethyl-hexa-2,4-dien-1-ol

: 141292-99-1
1-Acetoxy-4-benzyloxymethyl-2-[(E)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propenyl]-5-methyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 12 steps

1: 100 percent / DMSO

2: 83 percent / CH₂Cl₂

3: 95 percent / DIBAH

4: 93 percent / imidazole

5: 88 percent / chiral N-tosyl-4-methylindol-3-yl-oxazaborolidin-3-one / CH₂Cl₂ / 8 h / -78 - -40 °C

6: 99 percent / NaBH₄ / methanol

7: 98 percent / NaOMe / methanol / 5 h / Ambient temperature

8: 96 percent / NaOH / 2-methyl-propan-2-ol

9: MCPBA / CH₂Cl₂

10: 90 percent / NaOAC / 125 °C

11: 90 percent / NaClO₂ / 2-methyl-propan-2-ol; H₂O

12: 100 percent

With 1H-imidazole; sodium hydroxide; sodium chlorite; sodium tetrahydroborate; sodium methylate; sodium acetate; diisobutylaluminium hydride; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; chiral N-tosyl-4-methylindol-3-yl-oxazaborolidin-3-one; In methanol; dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/jo00037a005