DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-TITANIUM(IV)

Base Information

• Chemical Name: DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-TITANIUM(IV)
• CAS No.: 83462-45-7
• Molecular Formula: C₂₀H₂₄Cl₂Ti
• Molecular Weight: 383.197
• Mol file: 83462-45-7.mol

Synonyms:Titanium,dichloro[1,2-ethanediylbis[(1,2,3,3a,7a-h)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]-,stereoisomer; 1H-Indene, 1,1'-(1,2-ethanediyl)bis[4,5,6,7-tetrahydro-,titanium complex

Chemical Property of DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-TITANIUM(IV)

Chemical Property:

• Melting Point: 175-180oC(lit.)
• PSA: 0.00000
• LogP: 7.44240

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dichloro[(R,R)-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(IV) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Dichloro[(R,R)-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(IV) is used in preparation of Organometallic complexes of titanium.

Technology Process of DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-TITANIUM(IV)

There total 1 articles about DICHLORO-(S,S)-ETHYLENEBIS-(4,5,6,7-TETRAHYDRO-1-INDENYL)-TITANIUM(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylene-bis(4,5,6,7-tetrahydro-(S)-1-indenyl)titanium(IV)-(S)-1'.1''-bi-2-naphtholate (143063-72-3,83417-93-0) → (S,S)-ethylene-bis(4,5,6,7-tetrahydro-1-indenyl)titanium dichloride (83461-84-1,83417-94-1,83462-46-8,83462-45-7,112531-75-6)

Guidance literature:

With CH₃Li; HCl; In toluene; suspn. of Ti complex in petroleum ether/toluene treated with MeLi , then added gaseous HCl;

DOI:10.1016/S0022-328X(00)89067-1

upstream raw materials:

ethylene-bis(4,5,6,7-tetrahydro-(S)-1-indenyl)titanium(IV)-(S)-1'.1''-bi-2-naphtholate

Refernces