4',4''''-(5-METHYL-1,3-PHENYLENE)BIS-2,2':6',2''-TERPYRIDINE

Base Information

• Chemical Name: 4',4''''-(5-METHYL-1,3-PHENYLENE)BIS-2,2':6',2''-TERPYRIDINE
• CAS No.: 258834-70-7
• Molecular Formula: C37H26 N6
• Molecular Weight: 554.654
• Mol file: 258834-70-7.mol

Synonyms:4’,4’’’’-(5-METHYL-1,3-PHENYLENE)BIS-2,2’:6’,2’’-TERPYRIDINE

Chemical Property of 4',4''''-(5-METHYL-1,3-PHENYLENE)BIS-2,2':6',2''-TERPYRIDINE

Chemical Property:

• Boiling Point: 709.5°Cat760mmHg
• Flash Point: 385.4°C
• PSA: 77.34000
• Density: 1.214g/cm³
• LogP: 8.36700

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4',4''''-(5-METHYL-1,3-PHENYLENE)BIS-2,2':6',2''-TERPYRIDINE

There total 1 articles about 4',4''''-(5-METHYL-1,3-PHENYLENE)BIS-2,2':6',2''-TERPYRIDINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

2-acetylpyridine (1122-62-9) + 5-methylbenzene-1,3-dicarboxaldehyde (1805-67-0) → 1,3-bis(2,2':6',2''-terpyridin-4'-yl)-5-methylbenzene (258834-70-7)

Guidance literature:

2-acetylpyridine; 5-methylbenzene-1,3-dicarboxaldehyde; With sodium hydroxide;

With ammonium acetate; acetic acid;

DOI:10.1002/(SICI)1521-3773(19991216)38:24<3717::AID-ANIE3717>3.0.CO;2-C

Reference yield: 99.0%

cadmium(II) nitrate tetrhydrate + 1,3-bis(2,2':6',2''-terpyridin-4'-yl)-5-methylbenzene (258834-70-7) → 6Cd(2+)*6(CH3C6H3(C5H2N(C5H4N)2)2)*12NO3(1-)=Cd6(CH3C6H3(C5H2N(C5H4N)2)2)6(NO3)12

Guidance literature:

In methanol; chloroform; react. ligand with Cd salt in CHCl3/methanol 3:2 at 25°C for 1 h;

DOI:10.1021/ja907262c

Reference yield: 40.0%

[(RuCl3)2CH3C6H3(C15H10N3)2] (258834-74-1) + 1,3-bis(2,2':6',2''-terpyridin-4'-yl)-5-methylbenzene (258834-70-7) → 6Ru(2+)*6CH3C6H3(C15H10N3)2*12Cl(1-) = [Ru6(CH3C6H3(C15H10N3)2)6]Cl12

Guidance literature:

With N-ethylmorpholine;; In not given;

DOI:10.1002/(SICI)1521-3773(19991216)38:24<3717::AID-ANIE3717>3.0.CO;2-C

upstream raw materials:

2-acetylpyridine

5-methylbenzene-1,3-dicarboxaldehyde

Refernces

• 1、 Newkome, George R.,Cho, Tae Joon,Moorefield, Charles N.,Cush, Randy,Russo, Paul S.,Godinez, Luis A.,Saunders, Mary Jane,Mohapatra, Prabhu. "Hexagonal terpyridine-ruthenium and -iron macrocyclic complexes by stepwise and self-assembly procedures". . p. 2946 - 2954. Retrieved 2007/10/03.