mer-(BDPP)TaCl₃

Base Information

Chemical Name:mer-(BDPP)TaCl₃
CAS No.:167393-97-7
Molecular Formula:C₃₁H₄₁Cl₃N₃Ta
Molecular Weight:742.994
Hs Code.:

Synonyms:mer-(BDPP)TaCl₃

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Chemical Property of mer-(BDPP)TaCl₃

Chemical Property:

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Technology Process of mer-(BDPP)TaCl₃

There total 2 articles about mer-(BDPP)TaCl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 167393-96-6
C₅H₃N(CH₂N(C₆H₃(CH(CH₃)2)2)(Si(CH₃)3))2

: 7721-01-9
tantalum pentachloride

: 167393-97-7
mer-(BDPP)TaCl₃

Guidance literature:: In benzene; N2-atmosphere; excess py-deriv., portion-wise addn. of TaCl5 at 23°C, heating (80°C, 12 h); evapn. (vac.), dissolving in THF, filtration (Celite), filtrate evapn. (vac.), washing (hexane); elem. anal.;
DOI:10.1021/om970593v

Reference yield:

: 167393-96-6
C₅H₃N(CH₂N(C₆H₃(CH(CH₃)2)2)(Si(CH₃)3))2

: 7721-01-9
tantalum pentachloride

: 167393-97-7
Ta(Cl)3((((CH₃)2CH)2C₆H₃NCH₂)2C₅H₃N)

Guidance literature:: In benzene; byproducts: Me3SiCl; 80°C; elem. anal.;
DOI:10.1021/om00007a013

Reference yield: 82.0%

: 928-49-4
hex-3-yne

: 167393-97-7
mer-(BDPP)TaCl₃

: 167393-99-9
(BDPP)Ta(η(2)-EtCCEt)Cl

Guidance literature:: With Na/Hg; In toluene; N2-atmosphere; excess of alkyne; addn. of Na/Hg (excess), stirring (12 h); decantation from Hg, filtration (Celite), filtrate evapn. (vac.), dissolving in min. amt. of Et2O, crystn. on cooling (-30°C, 12 h), filtration, drying (vac.); elem. anal.;
DOI:10.1021/om970593v