{3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

Base Information

Chemical Name:{3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol
CAS No.:628698-02-2
Molecular Formula:C₄₁H₅₆O₁₃
Molecular Weight:756.888
Hs Code.:

Synonyms:{3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

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Chemical Property of {3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

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Technology Process of {3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

There total 4 articles about {3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 510754-08-2
2-(4-Bromomethyl-benzyloxymethyl)-1,4,7,10-tetraoxa-cyclododecane

: 29654-55-5
5-(hydroxymethyl)benzene-1,3-diol

: 628698-02-2
{3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

Guidance literature:: With potassium carbonate; 2-Benzyloxymethyl-1,4,7,10,13,16-hexacyclooctadecan; In acetone; for 72h; Heating;
DOI:10.1016/j.tet.2005.06.037

Reference yield:

: 510754-07-1
[4-(1,4,7,10-Tetraoxa-cyclododec-2-ylmethoxymethyl)-phenyl]-methanol

: 628698-02-2
{3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / PBr₃ / CHCl₃ / 1 h / 20 °C

2: 94 percent / benzyloxymethyl-18-crown-6; potassium carbonate / acetone / 72 h / Heating

With phosphorus tribromide; potassium carbonate; 2-Benzyloxymethyl-1,4,7,10,13,16-hexacyclooctadecan; In chloroform; acetone;
DOI:10.1016/j.tet.2005.06.037

Reference yield:

: 510754-06-0
4-(12-crown-4-methoxymethyl)benzoic acid methyl ester

: 628698-02-2
{3,5-Bis-[4-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxymethyl)-benzyloxy]-phenyl}-methanol

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / LiAlH₄ / tetrahydrofuran / 20 h / Heating

2: 77 percent / PBr₃ / CHCl₃ / 1 h / 20 °C

3: 94 percent / benzyloxymethyl-18-crown-6; potassium carbonate / acetone / 72 h / Heating

With lithium aluminium tetrahydride; phosphorus tribromide; potassium carbonate; 2-Benzyloxymethyl-1,4,7,10,13,16-hexacyclooctadecan; In tetrahydrofuran; chloroform; acetone;
DOI:10.1016/j.tet.2005.06.037