29654-55-5Relevant articles and documents
Resorcinarenes as templates: A general strategy for the synthesis of large macrocycles
Li, Xuehe,Upton, Thomas G.,Gibb, Corinne L. D.,Gibb, Bruce C.
, p. 650 - 651 (2003)
The concept that resorcinarenes can be used as templates for the synthesis of large macrocycles is introduced. By way of example, previously inaccessible, aromatic crown ethers compounds are synthesized. Copyright
Synthesis of 3, 5 - dihydroxy benzaldehyde method (by machine translation)
-
Paragraph 0030-0037, (2019/10/04)
The invention discloses a method for synthesizing 3, 5 - dihydroxy benzaldehyde of the method, the synthetic route is: first 3, 5 - dihydroxy benzoic acid sodium borohydride, dimethyl sulfate, boric acid under the action of the three methyl ester intermediate B obtained, then intermediate B in chromium trioxide and sulfuric acid to obtain compound under the action of the C, i.e. 3, 5 - dihydroxy benzaldehyde; reaction is: The invention of mild synthetic conditions, the reaction yield is high, and the process of the method is simple, the raw material is cheap, simple and convenient operation, is extremely suitable for industrial production, has a very wide range of industrial application and market value. (by machine translation)
Synthesis method of resveratrol
-
Paragraph 0030; 0033; 0034, (2016/12/01)
The invention provides a synthesis method of resveratrol.The method includes the steps of dissolving 3,5-dihydroxybenzoic acid in solvent, conducting reaction on sodium borohydride and Lewis acid to obtain 3,5-dihydroxy-benzyl alcohol, conducting reaction on 3,5-dihydroxy-benzyl alcohol and triphenylphosphine hydrobromic acid in certain solvent to obtain corresponding phosphonium, and making the obtained phosphonium react with p-hydroxy benzaldehyde under the effect of strong alkali to directly obtain the product resveratrol.The preparation method includes few steps, precious metal catalysts are prevented from being used in protection and deprotection processes of phenolic hydroxyl groups in the technology, cost is low, operation is easy, reaction conditions are easy to achieve, and industrial production is facilitated.