[Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

Base Information

Chemical Name:[Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]
CAS No.:301336-72-1
Molecular Formula:C₂₆H₂₂S₂Zr
Molecular Weight:489.817
Hs Code.:

Synonyms:[Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

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Chemical Property of [Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

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Technology Process of [Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

There total 1 articles about [Zr(η5-C5H5)(η5-C9H7)(SC6H5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 80155-52-8
(η5-cyclopentadienyl)(η5-indenyl) zirconium(IV) dichloride

: 2973-86-6
lithium thiophenoxide

: 301336-72-1
[Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

Guidance literature:: In tetrahydrofuran; diethyl ether; Ar; dropwise addn. of C6H5SLi/THF to a suspn. of Zr complex in Et2O at -78°C under stirring, mixt. stirred and allowed to warm at room temp. in 10 h, solvent removed under reduced pressure; residue extd. with toluene, filtered, solvent removed under reduced pressure, solid cooled to -196°C, crushed to powder, diethyl ether added, warmed to 35°C, pentane added, cooled to -18°C slowly for 48 h; ppt.;
DOI:10.1016/S0022-328X(00)00253-9

Reference yield: 67.0%

: 80155-52-8
(η5-cyclopentadienyl)(η5-indenyl) zirconium(IV) dichloride

: 301336-72-1
[Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

: 207917-44-0
[Zr(η5-C5H5)(η5-C9H7)(SC6H5)Cl]

Guidance literature:: With LiCl; In tetrahydrofuran; Ar atmosphere; addn of THF to C14H12Cl2Zr, C26H22S2Zr and LiCl at room temp., mixt. stirred at 40°C for 6 h; solvent removed under reduced pressure, pentane added, suspn. stirred at 40°C for 1 h, filtered, concn., cooled to -18°C for 64 h, ppt.;
DOI:10.1016/S0022-328X(00)00253-9

Reference yield:

: (+)-β-chlorodiisopinocampheylborane

: 301336-72-1
[Zr(η5-C5H5)(η5-C9H7)(SC6H5)2]

: 207917-44-0
[Zr(η5-C5H5)(η5-C9H7)(SC6H5)Cl]

: (C₁₀H₁₇)2B(SC₆H₅)

Guidance literature:: In toluene; to toluene soln. of C26H22S2Zr toluene soln. of (C10H17)2BCl was added,stirred overnight; solvent removed in vac., C20H17ClSZr not isolated, detected by NMR;
DOI:10.1016/S0022-328X(00)00253-9