(+/-)-curcuquinone

Base Information

• Chemical Name: (+/-)-curcuquinone
• CAS No.: 78964-28-0
• Molecular Formula: C₁₅H₂₀O₂
• Molecular Weight: 232.323
• Mol file: 78964-28-0.mol

Synonyms:(+/-)-curcuquinone

Chemical Property of (+/-)-curcuquinone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)-curcuquinone

There total 38 articles about (+/-)-curcuquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2,5-bis(methoxymethoxy)-4-(1,5-dimethylhex-4-enyl)toluene (170235-99-1) → (+/-)-curcuquinone (78964-28-0)

Guidance literature:

With ammonium cerium(IV) nitrate; In water; acetonitrile; for 2h;

DOI:10.1021/jo035778s

Reference yield: 83.0%

1-(2,5-dimethoxy-4-methylphenyl)ethyl diisopropylcarbamate (78920-00-0) → (+/-)-curcuquinone (78964-28-0)

Guidance literature:

With ammonium cerium(IV) nitrate; In water; acetonitrile; for 2h;

DOI:10.1021/jo035778s

Reference yield: 70.0%

(+/-)-curcuhydroquinone (78964-27-9) → (+/-)-curcuquinone (78964-28-0)

Guidance literature:

With silver(II) oxide; nitric acid; In 1,4-dioxane; for 0.166667h; Ambient temperature;

DOI:10.1021/jo00336a006

upstream raw materials:

(1'Z)-2-(1',5'-dimethylhexa-1',4'-dienyl)-5-methylbenzene-1,4-diol diacetate

(1'E)-2-(1',5'-dimethylhexa-1',4'-dienyl)-5-methylbenzene-1,4-diol diacetate

(+/-)-curcuhydroquinone

1-(2,5-dimethoxy-4-methylphenyl)ethyl diisopropylcarbamate

Downstream raw materials:

(+/-)-curcuhydroquinone

Refernces

• 1、 Green, Jason C.,Pettus, Thomas R. R.. "An oxidative dearomatization-induced [5 + 2] cascade enabling the syntheses of α-cedrene, α-pipitzol, and sec -cedrenol". supporting information; experimental part. p. 1603 - 1608. Retrieved 2011/04/16.
• 2、 Vyvyan, James R.,Loitz, Celeste,Looper, Ryan E.,Mattingly, Cheryl S.,Peterson, Emily A.,Staben, Steven T.. "Synthesis of Aromatic Bisabolene Natural Products via Palladium-Catalyzed Cross-Couplings of Organozine Reagents". . p. 2461 - 2468. Retrieved 2007/10/03.