4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine

Base Information

• Chemical Name: 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine
• CAS No.: 1196447-20-7
• Molecular Formula: C₃₃H₄₈N₂O₁₁
• Molecular Weight: 648.751
• Mol file: 1196447-20-7.mol

Synonyms:4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine

Chemical Property of 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine

There total 1 articles about 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrobenzaldehdye (555-16-8) + tetra-O-pivaloyl-β-D-galactopyranosylamine (108342-87-6) → 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine (1196447-20-7)

Guidance literature:

With acetic acid; In isopropyl alcohol; at 20 ℃; for 0.5h;

DOI:10.1002/adsc.200800406

Reference yield: 92.0%

2-methyl-1H-indole (95-20-5) + 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine (1196447-20-7) → N-[2-methyl-indol-3-yl-(4-nitrophenyl)methyl]-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)amine (1242070-76-3)

Guidance literature:

With indium(III) chloride; In dichloromethane; at -40 ℃; for 0.25h; Molecular sieve; Inert atmosphere;

DOI:10.1016/j.carres.2010.05.025

Reference yield: 90.0%

5-methoxylindole (1006-94-6) + 4-nitro-N-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl) benzylideneamine (1196447-20-7) → N-[5-methoxy-indol-3-yl-(4-nitrophenyl)methyl]-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)amine (1242070-77-4)

Guidance literature:

With indium(III) chloride; In dichloromethane; at -40 ℃; for 0.25h; Molecular sieve; Inert atmosphere;

DOI:10.1016/j.carres.2010.05.025

upstream raw materials:

4-nitrobenzaldehdye

tetra-O-pivaloyl-β-D-galactopyranosylamine

Downstream raw materials:

C₃₇H₅₉N₂O₁₄P

N-[indol-3-yl-(4-nitrophenyl)methyl]-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)amine

N-[2-methyl-indol-3-yl-(4-nitrophenyl)methyl]-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)amine

N-[6-chloro-indol-3-yl-(4-nitrophenyl)methyl]-(2,3,4,6-tetra-O-pivaloyl-β-D-galactosyl)amine