methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Base Information

Chemical Name:methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate
CAS No.:951168-39-1
Molecular Formula:C₂₇H₂₈O₉
Molecular Weight:496.514
Hs Code.:

Synonyms:methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Suppliers and Price of methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

There total 5 articles about methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 951168-38-0
methyl (3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosyl)uronate bromide

: 108-93-0
cyclohexanol

: 951168-39-1
methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Guidance literature:: With silver trifluoromethanesulfonate; In dichloromethane; at -78 - -35 ℃; for 5h;
DOI:10.1016/j.carres.2007.05.008

Reference yield:

: 103674-69-7
methyl 2,3,4-tri-O-benzoyl-1-bromo-1-deoxy-α-D-glucopyranuronate

: 951168-39-1
methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Guidance literature:: Multi-step reaction with 2 steps

1.1: Me₂NH; tetrabutylammonium bromide / dimethylformamide / -20 - -10 °C

1.2: 70 percent / MeOH; NBS / CH₂Cl₂ / 3 h / 25 °C

2.1: 85 percent / silver triflate / CH₂Cl₂ / 5 h / -78 - -35 °C

With tetrabutylammomium bromide; silver trifluoromethanesulfonate; dimethyl amine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.carres.2007.05.008

Reference yield:

: 487-44-5
D-(+)-glucuronic acid γ-lactone

: 951168-39-1
methyl (cyclohexyl 3,4-di-O-benzoyl-α-D-arabino-hexos-2-ulopyranosid)uronate

Guidance literature:: Multi-step reaction with 5 steps

1.1: HBr; HOAc

2.1: Me₂NH; tetrabutylammonium bromide / dimethylformamide / -20 - -10 °C

2.2: 70 percent / MeOH; NBS / CH₂Cl₂ / 3 h / 25 °C

3.1: 85 percent / silver triflate / CH₂Cl₂ / 5 h / -78 - -35 °C

With tetrabutylammomium bromide; hydrogen bromide; silver trifluoromethanesulfonate; acetic acid; dimethyl amine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.carres.2007.05.008