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Cyclohexanol
Cas No: 108-93-0
No Data 1 Kilogram 1000 Metric Ton/Year JINHUA HUAYI CHEMICAL CO., LTD. Contact Supplier
Cyclohexanol suppliers in China
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USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Cyclohexanol 99% supplier in China
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Cyclohexanol
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High Content Natural Extract Cyclohexanol HACCP manufacturer
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USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Factory Supply Cyclohexanol
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Cyclohexanol CAS: 108-93-0
Cas No: 108-93-0
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
Cyclohexanol CAS NO.108-93-0
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Organicintermediate99.8%Cyclohexanol108-93-0
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USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 2 Metric Ton/Day Hubei Jusheng Technology Co., Ltd., Contact Supplier
108-93-0 Cyclohexanol
Cas No: 108-93-0
USD $ 560.0-560.0 / Kilogram 1 Kilogram 100 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier

108-93-0 Usage

InChI:InChI=1/C6H12O/c7-6-4-2-1-3-5-6/h6-7H,1-5H2

108-93-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A17576)  Cyclohexanol, 99%    108-93-0 100ml 191.0CNY Detail
Alfa Aesar (A17576)  Cyclohexanol, 99%    108-93-0 500ml 234.0CNY Detail
Alfa Aesar (A17576)  Cyclohexanol, 99%    108-93-0 2500ml 739.0CNY Detail

108-93-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name cyclohexanol

1.2 Other means of identification

Product number -
Other names Hydralin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108-93-0 SDS

108-93-0Synthetic route

1,3-dimethoxy-2-hydroxy-benzene
91-10-1

1,3-dimethoxy-2-hydroxy-benzene

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen In decane at 349.84℃; under 22502.3 Torr; for 3h; Temperature; Autoclave;95.6%
With hydrogen In water at 160℃; for 6h;80%
Multi-step reaction with 3 steps
1: hydrogenchloride / 80 °C / 760.05 Torr / Electrochemical reaction
2: sodium hydroxide / 80 °C / Electrochemical reaction
3: hydrogenchloride / 80 °C / 760.05 Torr / Electrochemical reaction
View Scheme
1-((cyclohexyloxy)methyl)-4-methoxybenzene
156147-58-9

1-((cyclohexyloxy)methyl)-4-methoxybenzene

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With 4,4'-bipyridine; oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 80℃; under 3000.3 Torr; for 10h; Reagent/catalyst; Autoclave; Green chemistry;96%
With 4,4'-bipyridine; (phthalocyaninato)iron(II); oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 80℃; under 3000.3 Torr; for 10h; Autoclave;91%
With tert.-butylnitrite; oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone In monoethylene glycol diethyl ether at 120℃; under 1500.15 Torr; for 1.5h;
With tert.-butylnitrite; oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone In chlorobenzene at 100℃; under 760.051 Torr; for 3.5h;
aniline
62-53-3

aniline

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water; hydrogen In tert-butyl alcohol at 180℃; under 33003.3 Torr; for 8h; Reagent/catalyst; Pressure; Temperature; Molecular sieve; Autoclave;99.9%
With water; hydrogen at 160℃; Hydrogenation.Leiten ueber Nickel/Bimsstein;
phenol
108-95-2

phenol

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen; tetra(n-butyl)ammonium hydrogensulfate; rhodium colloidal catalyst In water at 36℃; under 180018 Torr; for 62h; pH=7.5; Catalytic hydrogenation;100%
In methanol; water100%
With hydrogen In water at 70℃; under 7500.75 Torr; for 0.25h;100%
cyclohexylboronic acid
4441-56-9

cyclohexylboronic acid

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; water; triethylamine In acetonitrile at 20℃; for 0.166667h;92%
With Fe2O3-SiO2 nanoparticles; air In water at 50℃; for 3h; Green chemistry;91%
With dihydrogen peroxide at 30℃; for 5h; Green chemistry;91%
cyclohexanone
108-94-1

cyclohexanone

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen; 5 percent Rh/MgO; magnesium oxide In water at 323℃; under 15001.2 Torr; Product distribution;100%
With Triethoxysilane; benzoic acid ethyl ester; cesium fluoride at 25℃; for 0.0166667h;100%
With zinc(II) tetrahydroborate In acetonitrile for 0.166667h; Ambient temperature;100%
cyclohexenone
930-68-7

cyclohexenone

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With Geotrichum candidum CCT 1205 whole cells In aq. phosphate buffer at 28℃; for 24h; pH=6.5; Enzymatic reaction;A 100%
B n/a
With hydrogen; In methanol at 30℃; under 735.5 Torr; for 5h;A 0.8%
B 98.2%
With C8H13O2S2(3-)*Na(1+)*Rh(1+)*H(1+); hydrogen In water; toluene at 60℃; under 15001.5 Torr; for 4h; Inert atmosphere; Schlenk technique; Autoclave;A 90%
B 9%
cyclohexane
110-82-7

cyclohexane

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With ferredoxin reductase; [2Fe–2S] ferredoxin; cytochrome P450 enzyme CYP101B1 In aq. buffer pH=7.4; Kinetics; Reagent/catalyst; Enzymatic reaction;95%
With C44H34N8O9Ti; dihydrogen peroxide; sodium hydrogencarbonate In acetonitrile at 80℃; under 760.051 Torr; for 4h; Catalytic behavior; Reagent/catalyst;93%
With perchloric acid; dihydrogen peroxide In water; acetonitrile; tert-butyl alcohol at 60℃; for 1h; stereoselective reaction;92%
2-methoxy-phenol
90-05-1

2-methoxy-phenol

A

cyclohexane
110-82-7

cyclohexane

B

2-methoxycyclohexanol
2979-24-0

2-methoxycyclohexanol

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With 5% active carbon-supported ruthenium; hydrogen; magnesium oxide In water at 159.84℃; under 11251.1 Torr; for 2h; Reagent/catalyst; Autoclave;A 7%
B 12%
C 79%
With Ni-doped silica; hydrogen In decalin at 140℃; under 22502.3 Torr; for 5h; Autoclave;A 16.8%
B 67.4%
C 8.9%
With hydrogen In decane at 20 - 250℃;A 25 %Chromat.
B 9 %Chromat.
C 8 %Chromat.
diphenylether
101-84-8

diphenylether

A

cyclohexane
110-82-7

cyclohexane

B

dicyclohexyl ether
4645-15-2

dicyclohexyl ether

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen; nickel In methyl cyclohexane at 90℃; under 37503.8 Torr; for 2.5h; chemoselective reaction;
With hydrogen In decalin at 120℃; under 15001.5 Torr; for 2h;
With hydrogen In methyl cyclohexane at 200℃; under 37503.8 Torr; for 0.666667h; Glovebox; Inert atmosphere; Autoclave;
With carbon dioxide; rhodium on carbon; hydrogen In tetrahydrofuran; water at 80℃; for 5h;
With hydrogen In water at 250℃; under 30003 Torr; for 2h;
1,3-diphenoxybenzene
3379-38-2

1,3-diphenoxybenzene

A

4-Phenoxyphenol
831-82-3

4-Phenoxyphenol

B

cyclohexanol
108-93-0

cyclohexanol

C

benzene
71-43-2

benzene

Conditions
ConditionsYield
With hydrogen In Hexadecane at 260℃; under 7600.51 Torr; for 5h; Autoclave;A 8.3%
B 9.5%
C 53.8%
phenol
108-95-2

phenol

A

cyclohexane
110-82-7

cyclohexane

B

cyclohexanol
108-93-0

cyclohexanol

C

benzene
71-43-2

benzene

Conditions
ConditionsYield
With phosphoric acid; 5 wt% ruthenium/carbon; hydrogen In water at 199.84℃; under 15001.5 Torr; for 2h; Autoclave;
With hydrogen In dodecane at 219.84℃; under 15001.5 Torr; Reagent/catalyst; Autoclave; Inert atmosphere;
With hydrogen In water at 200℃; under 7500.75 Torr; for 4h;
With hydrogen at 299.84℃;
cyclohexanone
108-94-1

cyclohexanone

A

1,1'-bicyclohexane-1,1'-diol
2888-11-1

1,1'-bicyclohexane-1,1'-diol

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water; titanium tetrachloride; zinc In diethyl ether at 40℃; for 15h; Solvent; Inert atmosphere;A 78.5%
B 21.5%
With samarium; N-Bromosuccinimide In methanol at 20℃; for 0.5h;A 70%
B 10%
With chloro-trimethyl-silane; samarium diiodide; tert-butylammonium hexafluorophosphate(V) In tetrahydrofuran Electrochemical reaction;A 59%
B 40%
With methanol; samarium; iodine; allyl bromide In tetrahydrofuran at 20℃; Inert atmosphere;A 40%
B 36%
With diethyl ether; sodium
phenol
108-95-2

phenol

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen at 160 - 200℃; under 1125.11 Torr; for 1h; Reagent/catalyst; Autoclave;A 94.2%
B 5.6%
With water In methanol at 220℃; under 22502.3 Torr; for 0.5h; Inert atmosphere; Microwave irradiation;A 87.34%
B 5.73%
With hydrogen; 1-butyl-3-methylimidazolium Tetrafluoroborate; Rh nanoparticles stabilized by poly(NVP-co-VBIMCl) at 75℃; under 30402 Torr; for 12h; Product distribution;A 29%
B 71%
cyclohexanone
108-94-1

cyclohexanone

A

cyclohexylamine
108-91-8

cyclohexylamine

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With ammonium hydroxide; hydrogen; magnesium oxide; ruthenium In water at 99.9℃; under 15001.2 Torr; Product distribution;A 6.5%
B 93.5%
With ammonia; hydrogen In methanol; ethanol at 100℃; under 37503.8 Torr; for 3h; Catalytic behavior; Reagent/catalyst; Autoclave;A 93.4%
B 6.6%
With ammonia; hydrogen In methanol at 80℃; for 6h; Autoclave;A 91%
B 9%
diphenylether
101-84-8

diphenylether

A

dicyclohexyl ether
4645-15-2

dicyclohexyl ether

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With platinum on activated charcoal; water; aluminium at 20 - 80℃; for 36h; Sealed tube;A 17%
B 67 %Chromat.
With hydrogen; Rh on carbon In methanol at 20℃; under 760.051 Torr; for 2.5h;
With carbon dioxide; rhodium on carbon; hydrogen In tetrahydrofuran; water at 80℃; for 5h; Solvent;
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; C23H36N(1+)*BF4(1-); potassium tert-butylate; hydrogen In tetrahydrofuran at 25℃; under 5168.35 Torr; for 2h; chemoselective reaction;A 70 %Chromat.
B 30 %Chromat.
With hydrogen In water at 80℃; under 11251.1 Torr; for 24h;A 82 %Chromat.
B 18 %Chromat.
2,3,4,5,6-pentafluoroaniline
771-60-8

2,3,4,5,6-pentafluoroaniline

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water In aq. phosphate buffer at 25℃; for 7.5h; pH=2.7 - 3.2; Electrochemical reaction;A 77%
B 22%
4-fluoroaniline
371-40-4

4-fluoroaniline

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water In aq. phosphate buffer at 25℃; for 1.5h; pH=2.7 - 3.2; Electrochemical reaction;A 78%
B 22%
cyclohexane
110-82-7

cyclohexane

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With Fe2(4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate); 1-(tert-butylsulfonyl)-2-iodosylbenzene In [D3]acetonitrile at 20℃; for 1.5h;A 100%
B 100%
With 3-chloro-benzenecarboperoxoic acid; [Ni2(L2H2)(OAc)2] at 20℃; for 1h;A 7%
B 93%
With 3-chloro-benzenecarboperoxoic acid; (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride In dichloromethane; acetonitrile for 1h; Product distribution; Ambient temperature; other catalysts; kinetic isotope effect;A 2%
B 89%
cyclohexene
110-83-8

cyclohexene

A

cyclohexenone
930-68-7

cyclohexenone

B

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

C

cyclohexanone
108-94-1

cyclohexanone

D

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With dihydrogen peroxide In isopropyl alcohol at 50℃; for 15h; Further byproducts given;A 25.9%
B 3.3%
C 2.3%
D 4.1%
With hydrogen; oxygen at 100℃;A 0.09%
B 0.03%
C 0.02%
D 0.01%
With tert.-butylhydroperoxide In water at 70 - 80℃; under 760.051 Torr; for 6h; Catalytic behavior;
With tert.-butylhydroperoxide In water at 70 - 80℃; under 760.051 Torr; for 6h; Catalytic behavior;
4-Phenoxyphenol
831-82-3

4-Phenoxyphenol

A

cyclohexanol
108-93-0

cyclohexanol

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
With hydrogen In Hexadecane at 200℃; under 7600.51 Torr; for 1h; Reagent/catalyst; Autoclave;A 28.8 %Chromat.
B 23.8 %Chromat.
With hydrogen In Hexadecane at 200℃; under 7600.51 Torr; for 1h; Reagent/catalyst; Autoclave;A 31.2 %Chromat.
B 35 %Chromat.
With hydrogen In Hexadecane at 200℃; under 7600.51 Torr; for 1h; Reagent/catalyst; Autoclave;
3-fluorophenol
372-20-3

3-fluorophenol

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water In aq. phosphate buffer at 25℃; for 1.5h; pH=2.7 - 3.2; Electrochemical reaction;A 33%
B 66%
2-(2-((cyclohexyloxy)methoxy)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(2-((cyclohexyloxy)methoxy)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With urea hydrogen peroxide adduct In [D3]acetonitrile at 20℃; pH=8;84%
With urea hydrogen peroxide adduct In aq. phosphate buffer; [D3]acetonitrile; water-d2 at 20℃; for 0.0333333h; pH=8;84 %Spectr.
furfural
98-01-1

furfural

A

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

B

2-methylfuran
534-22-5

2-methylfuran

C

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

D

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With Pd catalyst supported on CMK-5 mesoporous carbon In isopropyl alcohol at 180℃; under 15001.5 Torr; for 5h; Autoclave;A 16.8%
B 8.9%
C 34%
D 21.1%
With Pd catalyst supported on CMK-5 mesoporous carbon In isopropyl alcohol at 180℃; under 15001.5 Torr; for 5h; Autoclave;A 31.5%
B 13.4%
C 20.3%
D 16.3%
furfural
98-01-1

furfural

A

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

B

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With Pd catalyst supported on Vulcan In isopropyl alcohol at 180℃; under 15001.5 Torr; for 5h; Autoclave;A 7.2%
B 24.3%
C 11.6%
With Pd catalyst supported on MSU-F-C mesoporous carbon In isopropyl alcohol at 180℃; under 15001.5 Torr; for 5h; Autoclave;A 9.4%
B 19.8%
C 23.1%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

A

cyclohexane
110-82-7

cyclohexane

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h;A 5.2%
B 62.4%
With ethanol; platinum at 20℃; Hydrogenolyse;
With dihydrogen hexachloroplatinate; hydrogen; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at 60℃; under 7500.75 Torr; for 15h; Autoclave;
methoxybenzene
100-66-3

methoxybenzene

A

2-methoxycyclohexane
931-56-6

2-methoxycyclohexane

B

cyclohexane
110-82-7

cyclohexane

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen In decalin at 20 - 220℃; under 37503.8 - 45004.5 Torr; Inert atmosphere; Autoclave;A 72%
B 12%
C n/a
With 5% active carbon-supported ruthenium; hydrogen; magnesium oxide In water at 159.84℃; under 11251.1 Torr; for 2h;A 69%
B 9%
C 21%
With hydrogen In Hexadecane at 280℃; under 36003.6 Torr; for 6h; Catalytic behavior; Kinetics;A 35.38%
B 7.51%
C 5.52%
cyclohexyloxy(triethoxy)silane
18027-46-8

cyclohexyloxy(triethoxy)silane

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water; sodium hydroxide In tetrahydrofuran; methanol at 50℃; for 48h;
With water; sodium hydroxide In methanol
With sodium hydroxide In methanol at 60℃; for 24h; Inert atmosphere; Schlenk technique;
2-methoxy-phenol
90-05-1

2-methoxy-phenol

A

cyclohexanol
108-93-0

cyclohexanol

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With 5 wt% ruthenium/carbon; hydrogen In water at 199.84℃; under 15001.5 Torr; for 4h; Autoclave;
With hydrogen In water at 230℃; under 7500.75 Torr; for 4h; Reagent/catalyst; Autoclave;
2-fluorophenol
367-12-4

2-fluorophenol

A

cyclohexanone
108-94-1

cyclohexanone

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water In aq. phosphate buffer at 25℃; for 1.5h; pH=2.7 - 3.2; Electrochemical reaction;A 40%
B 57%
cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With lithium borohydride; 9-methoxy-9-BBN In diethyl ether at 25℃; for 0.25h; Product distribution;100%
With sodium aluminum tetrahydride In tetrahydrofuran at 0℃; for 6h;100%
With LiCrH4*2LiCl*2THF In tetrahydrofuran at 25℃; for 12h;100%
2-(cyclohexyloxy)tetrahydrofuran
1918-61-2

2-(cyclohexyloxy)tetrahydrofuran

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In ethanol for 1h; Ambient temperature;100%
2-methoxycyclohexane
931-56-6

2-methoxycyclohexane

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With tetrachlorosilane; sodium iodide In dichloromethane; acetonitrile for 4h; Heating;100%
With phenylthiotrimethylsilane; tetra-(n-butyl)ammonium iodide; zinc(II) iodide In 1,2-dichloro-ethane at 60℃; for 8h;97 % Chromat.
(R)-methoxytrifluoromethylphenylacetyl chloride
20445-33-4, 39637-99-5

(R)-methoxytrifluoromethylphenylacetyl chloride

cyclohexanone
108-94-1

cyclohexanone

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With bis(phosphine)rhodium; coimmobilized horse liver alcohol dehydrogenase and D- and L-lactate dehydrogenase; NAD; sodium lactate In water for 192h; pH 8.0;100%
C24H44BO4(1-)*Na(1+)

C24H44BO4(1-)*Na(1+)

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With water100%
cyclohexyl hydroperoxide
766-07-4

cyclohexyl hydroperoxide

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With triphenylphosphine100%
With triphenylphosphine
With triphenylphosphine In diethyl ether
With triphenylphosphine
cyclohexenone
930-68-7

cyclohexenone

A

hexahydro-2H-oxepin-2-one
502-44-3

hexahydro-2H-oxepin-2-one

B

cyclohexanone
108-94-1

cyclohexanone

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With Geotrichum candidum CCT 1205 whole cells In aq. phosphate buffer at 28℃; for 24h; pH=6.5; Baeyer-Villiger Ketone Oxidation; Enzymatic reaction;A n/a
B 100%
C n/a
(benzyloxy)benzene
946-80-5

(benzyloxy)benzene

A

toluene
108-88-3

toluene

B

cyclohexanol
108-93-0

cyclohexanol

C

phenol
108-95-2

phenol

Conditions
ConditionsYield
With Ni0.85Rh0.15; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst;A 100%
B 5%
C 79%
With isopropyl alcohol at 150℃; under 7500.75 Torr; for 48h; Inert atmosphere; Autoclave;A 100%
B 12.2%
C 87.5%
With isopropyl alcohol at 150℃; under 7500.75 Torr; for 3h; Catalytic behavior; Temperature; Inert atmosphere; Autoclave;A 100%
B 73.1%
C 22.4%
With Ru0.6Ni0.4; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst;A 98%
B 61%
C 6%
With hydrogen In n-heptane at 140℃; under 750.075 Torr; for 6h; Catalytic behavior;A 34 %Chromat.
B 12 %Chromat.
C 22 %Chromat.
diphenylether
101-84-8

diphenylether

A

cyclohexane
110-82-7

cyclohexane

B

cyclohexanol
108-93-0

cyclohexanol

C

benzene
71-43-2

benzene

Conditions
ConditionsYield
With isopropyl alcohol at 150℃; under 7500.75 Torr; for 12h; Inert atmosphere; Autoclave;A 25.1%
B 100%
C 74.9%
With isopropyl alcohol at 160℃; for 15h; Autoclave; Inert atmosphere;
With isopropyl alcohol at 150℃; for 10h; Catalytic behavior; Reagent/catalyst; Temperature; Sealed tube;A 24.6 %Chromat.
B 47.8 %Chromat.
C 24.3 %Chromat.
With isopropyl alcohol at 150℃; for 6h; Temperature; Sealed tube;A 15.2 %Chromat.
B 17.7 %Chromat.
C 5.8 %Chromat.
2-(cyclohexyloxy)tetrahydro-2H-pyran
709-83-1

2-(cyclohexyloxy)tetrahydro-2H-pyran

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With methanol; zirconium(IV) chloride at 20℃; for 5h;99%
silica-supported prop-1-ylsulfonic acid In methanol99.1%
Nafion-H In methanol for 3h;98%
2-methoxy-phenol
90-05-1

2-methoxy-phenol

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen In water at 160℃; for 10h; Temperature; Concentration; Reagent/catalyst;99%
With potassium hydroxide; Raney Ni-Al; water at 90℃; for 16h;90.8%
With acetic acid; platinum Hydrogenation;
allyl cyclohexyl carbonate
14289-72-6

allyl cyclohexyl carbonate

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With Fe3O4@SiO2-[(4-(5-O3Si-pentylcarbamoyl)-2-pyridinecarboxylato)CpRu(η3-C3H5)]PF6 In methanol at 30℃; for 1h; Inert atmosphere; chemoselective reaction;99%
With diethylamine; palladium diacetate; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile for 0.166667h; Ambient temperature;80%
[RuCp(η3-C3H5)(QA)]PF6, QA=quinaldic acid In methanol at 30℃; for 0.5h;99 % Spectr.
5-cyclohexyloxythianthreniumyl perchlorate

5-cyclohexyloxythianthreniumyl perchlorate

A

thianthrene-5-oxide
2362-50-7

thianthrene-5-oxide

B

Thianthrene
92-85-3

Thianthrene

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With sodium thiophenolate; thiophenol In acetonitrile for 2h; Product distribution; Substitution; elimination;A 5.1%
B 94%
C 99%
diphenylether
101-84-8

diphenylether

A

cyclohexane
110-82-7

cyclohexane

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine In toluene at 70℃; for 5h; Micellar solution;A 99%
B 99%
With Ru0.6Ni0.4; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst;A 92%
B 96%
With hydrogen In water at 110℃; under 7500.75 Torr; for 1h; Autoclave;
(benzyloxy)benzene
946-80-5

(benzyloxy)benzene

A

methyl cyclohexane
82166-21-0

methyl cyclohexane

B

toluene
108-88-3

toluene

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen In isopropyl alcohol at 120℃; for 2h;A 28%
B 72%
C 99%
With Rh0.6Ni0.4; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst;A 35%
B 63%
C 95%
With 10% Pd/C; hydrogen In hexane at 160℃; under 30003 Torr; for 2h; Autoclave;
With isopropyl alcohol at 170℃; for 15h; Sealed tube;A 0.68 mmol
B 0.28 mmol
C 0.94 mmol
2-phenethoxybenzene
40515-89-7

2-phenethoxybenzene

A

ethyl-cyclohexane
1678-91-7

ethyl-cyclohexane

B

ethylbenzene
100-41-4

ethylbenzene

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen; lanthanum(lll) triflate In isopropyl alcohol at 120℃; for 2h;A 33%
B 66%
C 99%
With hydrogen In n-heptane at 160℃; under 750.075 Torr; for 6h; Catalytic behavior; Temperature;A 8 %Chromat.
B 92 %Chromat.
C 100 %Chromat.
With isopropyl alcohol at 170℃; under 7500.75 Torr; Inert atmosphere; Autoclave;
cyclohexenone
930-68-7

cyclohexenone

A

Cyclohex-2-enol
822-67-3

Cyclohex-2-enol

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With sodium tetrahydroborate; Nd(EBAB)Cl3 In methanol for 1h; Product distribution; Ambient temperature; other reagents: Ln(EBAB)Cl3, Ce(EBAB)Cl3, Pr(EBAB)Cl3, Sm(PBAB)Cl3, Yb(PBAB)Cl3, Lu(PBAB)Cl3;A 98.5%
B 1.5%
With N-tert-butylaminoborane In diethyl ether for 16h; Ambient temperature; Yields of byproduct given;A 87%
B n/a
With potassium hydroxide; hydrogen; RuCl2<(R)-binap>(dmf)n*(R,R)-1,2-diphenylethylenediamine In isopropyl alcohol at 28℃; under 3040 Torr; for 1h;A 65%
B 2%
Pentachlorophenol
87-86-5

Pentachlorophenol

A

cyclohexanol
108-93-0

cyclohexanol

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With nickel dichloride; RedAl In tetrahydrofuran at 68℃; for 2h; Product distribution; other dehalogenating systems, other reaction times and temperatures;A n/a
B 98%
trimethylsilyl cyclohexyl ether
13871-89-1

trimethylsilyl cyclohexyl ether

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With (Ppyz)Zr(BH4)2Cl2 In diethyl ether at 20℃; for 9h;98%
With Oxone In methanol for 0.4h; Heating;96%
With iron(III) chloride In acetonitrile for 0.0166667h; Product distribution; Ambient temperature; var. Lewis acids; other silyl ethers;95%
cis-2-(trimethylsilyl)cyclohexyl trifluoroacetate
80866-33-7

cis-2-(trimethylsilyl)cyclohexyl trifluoroacetate

A

cyclohexene
110-83-8

cyclohexene

B

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
In ethanol at 65℃; Kinetics; ΔH, ΔG, ΔS (excit.);A 98%
B n/a
In water at 60℃; Kinetics;A 9.2%
B n/a
cyclohexenone
930-68-7

cyclohexenone

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With borane-ammonia complex; Pd(SIPr)(PCy3) In isopropyl alcohol at 50℃; for 16h; Inert atmosphere; Glovebox;97%
With formic acid; C18H24ClIrN3 In water at 80℃; for 4h; Schlenk technique; Inert atmosphere;94%
With formic acid; C18H14ClN4O2Ru(1+)*Cl(1-); sodium formate In water at 60℃; for 20h; Inert atmosphere;90%
Cyclohex-2-enol
822-67-3

Cyclohex-2-enol

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen In methanol at 80℃; under 7500.75 Torr; for 20h; Autoclave;97%
With 1,1'-bis(diphenylphosphino)ferrocene; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; Butane-1,4-diol; potassium tert-butylate at 110℃; for 24h; Inert atmosphere;68%
With sodium tetrahydroborate; C11H18Cl2CoN2S; hydrogen In isopropyl alcohol at 100℃; under 37503.8 Torr; for 16h; Glovebox; Autoclave;47%
cyclohexenone
930-68-7

cyclohexenone

A

cyclohexanone
108-94-1

cyclohexanone

B

Cyclohex-2-enol
822-67-3

Cyclohex-2-enol

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With ammonium chloride In methanol Electrochemical reaction;A 96%
B 1%
C 1%
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 110℃; under 30400 Torr; for 4h;A 68%
B 1%
C 2%
With Li(1+)*C12H28AlO3(1-) In tetrahydrofuran; hexane at -78℃; for 3h; Yield given. Yields of byproduct given;
cyclohexanone
108-94-1

cyclohexanone

dimethyl amine
124-40-3

dimethyl amine

A

N-methylcyclohexylamine
100-60-7

N-methylcyclohexylamine

B

N,N-dimethyl-cyclohexanamine
98-94-2

N,N-dimethyl-cyclohexanamine

C

cyclohexanol
108-93-0

cyclohexanol

Conditions
ConditionsYield
With hydrogen at 160 - 220℃; under 67506.8 - 97509.8 Torr; for 100 - 1000h; Product distribution / selectivity;A 0.1%
B 96%
C 0.5%
With hydrogen at 160 - 180℃; under 63756.4 - 97509.8 Torr; for 100 - 400h; Product distribution / selectivity;A 0.1%
B 94%
C 2%
acetic anhydride
108-24-7

acetic anhydride

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl acetate
622-45-7

cyclohexyl acetate

Conditions
ConditionsYield
With iodine for 0.333333h; Ambient temperature;100%
With SBA-15-Ph-Pr-SO3H at 20℃; for 0.5h;100%
yttria-stabilized zirconia In acetonitrile for 4h; Heating;99%
acetic acid
64-19-7

acetic acid

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl acetate
622-45-7

cyclohexyl acetate

Conditions
ConditionsYield
zirconium(IV) oxide at 200℃; Heating; reflux, 5 h in liquid-phase; var. temp.: 130 deg C;100%
With β-cyclodextrin-SO3H In neat (no solvent) at 70℃; for 5h;99%
LaY zeolite at 116℃; for 10h; Acetylation;98%
cyanoacetic acid
372-09-8

cyanoacetic acid

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl 2-cyanoacetate
52688-11-6

cyclohexyl 2-cyanoacetate

Conditions
ConditionsYield
With sulfuric acid In benzene for 2.5h; Fischer esterification; Heating;100%
With sulfuric acid In chloroform for 5h; Reflux;78%
With sulfuric acid In toluene for 24h; Reflux;77%
With hydrocarbon; toluene-4-sulfonic acid unter Entfernung des entstehenden Wassers durch azeotrope Destillation;
chlorophosphoric acid diphenyl ester
2524-64-3

chlorophosphoric acid diphenyl ester

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl diphenyl phosphate
4281-67-8

cyclohexyl diphenyl phosphate

Conditions
ConditionsYield
With titanium(IV) tetrabutoxide; triethylamine In dichloromethane at 20℃; for 1h;100%
With titanium tetrachloride; triethylamine In tetrahydrofuran at 20℃; for 1h;97%
With pyridine N-oxide; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene In dichloromethane at 20℃; for 8h; Inert atmosphere;94%
cyclohexanol
108-93-0

cyclohexanol

Cyclohexanecarboxylic acid
98-89-5

Cyclohexanecarboxylic acid

cyclohexyl cyclohexanecarboxylate
15840-96-7

cyclohexyl cyclohexanecarboxylate

Conditions
ConditionsYield
zirconium(IV) oxide at 210℃; for 2h; in autoclave; 5 h, reflux in liquid-phase;100%
With dmap; iodine; di-2-thienyl carbonate In acetonitrile at 20℃; for 0.5h;89%
With dmap; 2-methyl-6-nitrobenzoic anhydride; triethylamine In dichloromethane at 20℃; for 20h;87%
cyclohexanol
108-93-0

cyclohexanol

Adipic acid
124-04-9

Adipic acid

Conditions
ConditionsYield
With oxygen; sodium nitrite In trifluoroacetic acid at 0 - 20℃; for 5h;100%
With oxygen; potassium nitrate; trifluoroacetic acid at 0 - 20℃; for 5.25h; Product distribution / selectivity;100%
With potassium nitrite; oxygen; trifluoroacetic acid at 0 - 20℃; for 5.25h; Product distribution / selectivity;100%
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