tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

Base Information

Chemical Name:tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane
CAS No.:524956-58-9
Molecular Formula:C₃₀H₄₁ClO₃Si
Molecular Weight:513.192
Hs Code.:

Synonyms:tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

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Chemical Property of tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

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Technology Process of tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

There total 7 articles about tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 524956-55-6
12-(tert-butyldiphenylsilanyloxy)-6-methoxymethoxydodeca-(2Z,4E,10Z)-trien-1-ol

: 524956-58-9
tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

Guidance literature:: With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine; In dichloromethane; at 20 ℃;
DOI:10.1139/v02-064

Reference yield:

: 119119-20-9
(2E,4Z)-6-(Tetrahydro-pyran-2-yloxy)-hexa-2,4-dienal

: 524956-58-9
tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1.1: tert-butyllithium / diethyl ether / 0.17 h / -78 °C

1.2: 92 percent / diethyl ether / 0.42 h / -78 - 20 °C

2.1: 97 percent / potassium bis(trimethylsilyl)amide / tetrahydrofuran / 2 h / 0 - 70 °C

3.1: 81 percent / pyridinium p-toluenesulfonate / propan-2-ol / 1 h / Heating

4.1: 91 percent / hexachloroacetone; triphenylphosphine / CH₂Cl₂ / 20 °C

With 1,1,1,3,3,3-hexachloro-propan-2-one; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; isopropyl alcohol;
DOI:10.1139/v02-064

Reference yield:

: 307497-58-1
(4Z)-6-(tert-butyldiphenylsilyloxy)-4-hexen-1-ol

: 524956-58-9
tert-butyl-(12-chloro-7-methoxymethoxydodeca-(2Z,8E,10Z)-trienyloxy)diphenylsilane

Guidance literature:: Multi-step reaction with 6 steps

1.1: triethylamine / CH₂Cl₂ / 1 h / 0 °C

2.1: 15.14 g / sodium iodide / acetone / 1.5 h / Heating

3.1: tert-butyllithium / diethyl ether / 0.17 h / -78 °C

3.2: 92 percent / diethyl ether / 0.42 h / -78 - 20 °C

4.1: 97 percent / potassium bis(trimethylsilyl)amide / tetrahydrofuran / 2 h / 0 - 70 °C

5.1: 81 percent / pyridinium p-toluenesulfonate / propan-2-ol / 1 h / Heating

6.1: 91 percent / hexachloroacetone; triphenylphosphine / CH₂Cl₂ / 20 °C

With 1,1,1,3,3,3-hexachloro-propan-2-one; tert.-butyl lithium; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; triethylamine; triphenylphosphine; sodium iodide; In tetrahydrofuran; diethyl ether; dichloromethane; isopropyl alcohol; acetone;
DOI:10.1139/v02-064