N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester

Base Information

• Chemical Name: N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester
• CAS No.: 1017587-77-7
• Molecular Formula: C₇₀H₇₂N₄O₁₆
• Molecular Weight: 1225.36
• Mol file: 1017587-77-7.mol

Synonyms:N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester

Chemical Property of N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester

There total 1 articles about N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

phenyl 2,6-di-O-benzyl-3,4-di-O-(4-methoxybenzyl)-1-thio-β-D-galactopyranoside + allyl N-(9-fluorenylmethoxycarbonyl)-[O-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1[*]3)]-L-serine (155177-85-8) → N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-β-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester (1017587-77-7) + N-(9-fluorenylmethoxycarbonyl)-O-[2,6-di-O-benzyl-3,4-di-O-(4-methoxyphenyl)methyl-α-D-galactopyranosyl-(1->3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl]-L-serine allyl ester (1017587-78-8)

Guidance literature:

phenyl 2,6-di-O-benzyl-3,4-di-O-(4-methoxybenzyl)-1-thio-β-D-galactopyranoside; allyl N-(9-fluorenylmethoxycarbonyl)-[O-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1[*]3)]-L-serine; With 4 A molecular sieve; sulfobromophthalein sodium; In various solvent(s); at -78 ℃; for 0.166667h;

With trifluoromethylsulfonic anhydride; In various solvent(s); at -78 ℃; for 0.5h; Further stages.;

DOI:10.1016/j.tet.2008.01.029

upstream raw materials:

allyl N-(9-fluorenylmethoxycarbonyl)-[O-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1[*]3)]-L-serine