Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

Base Information

Chemical Name:Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester
CAS No.:634611-89-5
Molecular Formula:C₂₁H₃₂O₂Si
Molecular Weight:344.569
Hs Code.:

Synonyms:Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

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Chemical Property of Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

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Technology Process of Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

There total 8 articles about Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 98-88-4
benzoyl chloride

: 634611-82-8
(Z)-(S)-6,7-Dimethyl-3-trimethylsilanylmethyl-octa-2,7-dien-1-ol

: 634611-89-5
Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

Guidance literature:: With pyridine; dmap; In dichloromethane; for 1h;
DOI:10.1002/ejoc.200300276

Reference yield:

: 73295-12-2
(S)-2,3-dimethyl-1,3-butanediol

: 634611-89-5
Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

Guidance literature:: Multi-step reaction with 8 steps

1.1: pyridine / 15 h / 0 °C

2.1: 14.8 g / mesyl chloride; Et₃N / diethyl ether / 15 h / 0 - 20 °C

3.1: LiI / tetrahydrofuran / 2 h / Heating

4.1: NaH; BuLi / tetrahydrofuran; hexane / 0.25 h / 0 °C

4.2: 40 percent / tetrahydrofuran; hexane / 1.5 h / 0 - 20 °C

5.1: NaH / tetrahydrofuran / 1.5 h / 0 - 20 °C

6.1: 2.67 g / Ni(acac)2 / tetrahydrofuran / 1 h / 0 °C

7.1: 85 percent / DIBALH / diethyl ether / 1 h / 0 °C

8.1: 99 percent / pyridine; DMAP / CH₂Cl₂ / 1 h

With pyridine; dmap; bis(acetylacetonate)nickel(II); n-butyllithium; sodium hydride; diisobutylaluminium hydride; methanesulfonyl chloride; triethylamine; lithium iodide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1002/ejoc.200300276

Reference yield:

: 93748-48-2
(S)-3-hydroxy-2,3-dimethylbutyl 4-methylbenzenesulfonate

: 634611-89-5
Benzoic acid (Z)-(S)-6,7-dimethyl-3-trimethylsilanylmethyl-octa-2,7-dienyl ester

Guidance literature:: Multi-step reaction with 7 steps

1.1: 14.8 g / mesyl chloride; Et₃N / diethyl ether / 15 h / 0 - 20 °C

2.1: LiI / tetrahydrofuran / 2 h / Heating

3.1: NaH; BuLi / tetrahydrofuran; hexane / 0.25 h / 0 °C

3.2: 40 percent / tetrahydrofuran; hexane / 1.5 h / 0 - 20 °C

4.1: NaH / tetrahydrofuran / 1.5 h / 0 - 20 °C

5.1: 2.67 g / Ni(acac)2 / tetrahydrofuran / 1 h / 0 °C

6.1: 85 percent / DIBALH / diethyl ether / 1 h / 0 °C

7.1: 99 percent / pyridine; DMAP / CH₂Cl₂ / 1 h

With pyridine; dmap; bis(acetylacetonate)nickel(II); n-butyllithium; sodium hydride; diisobutylaluminium hydride; methanesulfonyl chloride; triethylamine; lithium iodide; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;
DOI:10.1002/ejoc.200300276