diethyl cyclohexane-trans-1,2-dicarboxylate

Base Information

• Chemical Name: diethyl cyclohexane-trans-1,2-dicarboxylate
• CAS No.: 96836-97-4
• Molecular Formula: C₁₂H₂₀O₄
• Molecular Weight: 228.288
• Mol file: 96836-97-4.mol

Synonyms:diethyl cyclohexane-trans-1,2-dicarboxylate

Chemical Property of diethyl cyclohexane-trans-1,2-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl cyclohexane-trans-1,2-dicarboxylate

There total 5 articles about diethyl cyclohexane-trans-1,2-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-1,2-bis(ethoxycarbonyl)-4-cyclohexene (4841-85-4,5048-50-0,13043-60-2,56000-17-0) → diethyl cyclohexane-trans-1,2-dicarboxylate (96836-97-4,17351-22-3)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol;

DOI:10.1002/mrc.1270160403

Reference yield:

diethyl Fumarate (623-91-6) → diethyl cyclohexane-trans-1,2-dicarboxylate (96836-97-4,17351-22-3)

Guidance literature:

Multi-step reaction with 2 steps

1: hydroquinone / ethanol / 130 °C / in sealed bomb reactor

2: H₂ / 5percent Pd/C / ethanol

With hydrogen; hydroquinone; palladium on activated charcoal; In ethanol;

DOI:10.1002/mrc.1270160403

Reference yield:

diethyl 1,2,3,6-tetrahydrophthalate (13043-60-2) → diethyl cyclohexane-cis-1,2-dicarboxylate (17351-07-4,17351-22-3) + diethyl cyclohexane-trans-1,2-dicarboxylate (96836-97-4,17351-22-3)

Guidance literature:

With hydrogen; In ethyl acetate; at 100 ℃; for 4h; under 15001.5 Torr;

DOI:10.1002/anie.201801287

upstream raw materials:

trans-1,2-bis(ethoxycarbonyl)-4-cyclohexene

diethyl Fumarate

diethyl 1,2,3,6-tetrahydrophthalate

Downstream raw materials:

(+/-)-1,1,3,3-tetraphenyl-trans-octahydro-isobenzofuran

trans-2-thiahydrindane

trans-1,2-bis(hydroxymethyl)cyclohexane di-p-toluene-sulfonate

<2-Diphenylmethylen-cyclohexyl>-diphenyl-methanol