(2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

Base Information

Chemical Name:(2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane
CAS No.:364597-29-5
Molecular Formula:C₃₃H₄₄O₃Si
Molecular Weight:516.796
Hs Code.:

Synonyms:(2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

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Technology Process of (2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

There total 4 articles about (2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 364597-27-3
(2S,3S,4S,6R,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methyl-4-(phenylseleno)nonane

: 364597-29-5
(2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

Guidance literature:: With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile);
DOI:10.1016/S0040-4039(01)00921-2

Reference yield:

: (4R)-5-benzyloxy-4-methylpent-2-enyl(tributyl)stannane

: 364597-29-5
(2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / SnCl₄ / 1 h / -78 °C

2: 62 percent / SnCl₄

3: 85 percent / Bu₃SnH / AIBN

With tri-n-butyl-tin hydride; tin(IV) chloride; 2,2'-azobis(isobutyronitrile); 3: reduction;
DOI:10.1016/S0040-4039(01)00921-2

Reference yield:

: 364597-23-9
(3S)-3-{[tert-butyl(diphenyl)silyl]oxy}butanal

: 364597-29-5
(2S,3R,6S,8S)-1-benzyloxy-8-tert-butyldiphenylsilyloxy-3,6-epoxy-2-methylnonane

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / SnCl₄ / 1 h / -78 °C

2: 62 percent / SnCl₄

3: 85 percent / Bu₃SnH / AIBN

With tri-n-butyl-tin hydride; tin(IV) chloride; 2,2'-azobis(isobutyronitrile); 3: reduction;
DOI:10.1016/S0040-4039(01)00921-2