(3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate

Base Information

• Chemical Name: (3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate
• CAS No.: 1006382-45-1
• Molecular Formula: C₂₁H₃₂O₃Si
• Molecular Weight: 360.569
• Mol file: 1006382-45-1.mol

Synonyms:(3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate

Chemical Property of (3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate

There total 1 articles about (3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H28O2Si (1006382-44-0) + benzoyl chloride (98-88-4) → (3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate (1006382-45-1)

Guidance literature:

With pyridine; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1002/anie.200704423

Reference yield: 91.0%

(3R)-3-{(1S)-1-methyl-2-[(trimethylsilyl)oxy]cyclohex-2-en-1-yl}butyl benzoate (1006382-45-1) → (3R)-3-{(1S)-1-methyl-2-oxocyclohex-3-en-1-yl}butyl benzoate (1006382-46-2)

Guidance literature:

With oxygen; palladium diacetate; In dimethyl sulfoxide; at 80 ℃; for 15h;

DOI:10.1002/anie.200704423

upstream raw materials:

C₁₄H₂₈O₂Si

benzoyl chloride

Downstream raw materials:

(3R)-3-{(1S)-1-methyl-2-oxocyclohex-3-en-1-yl}butyl benzoate