4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

Base Information

Chemical Name:4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester
CAS No.:128055-31-2
Molecular Formula:C₄₄H₅₅F₃O₇
Molecular Weight:752.912
Hs Code.:

Synonyms:4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

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Chemical Property of 4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

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Technology Process of 4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

There total 5 articles about 4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 111153-17-4
4-benzyloxy-biphenyl-4'-carboxylic acid chloride

: 128055-31-2
4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / 72 h / Ambient temperature

2: 87 percent / H₂ / 10percent Pd/C / ethanol / 5 h / Irradiation

3: 1.) NaH / 1.) THF, RT, 2 h, 2.) 50 deg C, 5 h

With pyridine; hydrogen; sodium hydride; palladium on activated charcoal; In ethanol; dichloromethane;
DOI:10.1021/ja00174a023

Reference yield:

: 111153-16-3
4'-(Benzyloxy)-biphenyl-4-carboxylic acid

: 128055-31-2
4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: thionyl chloride / 1 h / Heating

2: pyridine / CH₂Cl₂ / 72 h / Ambient temperature

3: 87 percent / H₂ / 10percent Pd/C / ethanol / 5 h / Irradiation

4: 1.) NaH / 1.) THF, RT, 2 h, 2.) 50 deg C, 5 h

With pyridine; thionyl chloride; hydrogen; sodium hydride; palladium on activated charcoal; In ethanol; dichloromethane;
DOI:10.1021/ja00174a023

Reference yield:

: 121170-47-6
(R)-(+)-4-hydroxybenzoic acid 1-trifluoromethylheptyl ester

: 128055-31-2
4'-[12-(2-Methyl-acryloyloxy)-dodecyloxy]-biphenyl-4-carboxylic acid 4-((R)-1-trifluoromethyl-heptyloxycarbonyl)-phenyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / CH₂Cl₂ / 72 h / Ambient temperature

2: 87 percent / H₂ / 10percent Pd/C / ethanol / 5 h / Irradiation

3: 1.) NaH / 1.) THF, RT, 2 h, 2.) 50 deg C, 5 h

With pyridine; hydrogen; sodium hydride; palladium on activated charcoal; In ethanol; dichloromethane;
DOI:10.1021/ja00174a023