1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

Base Information

Chemical Name:1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol
CAS No.:685888-10-2
Molecular Formula:C₃₈H₄₈O₆
Molecular Weight:600.796
Hs Code.:

Synonyms:1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

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Chemical Property of 1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

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Technology Process of 1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

There total 13 articles about 1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 3396-11-0
cesium acetate

: 685888-09-9
1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-tosyl-sn-glycerol

: 685888-10-2
1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

Guidance literature:: In dimethyl sulfoxide; N,N-dimethyl-formamide; for 72h;

Reference yield:

: 821-41-0
5-Hexen-1-ol

: 685888-10-2
1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

Guidance literature:: Multi-step reaction with 8 steps

1.1: 67 percent / PPh₃; imidazole; I₂ / CH₂Cl₂ / 2 h / 20 °C

2.1: 91 percent / nitromethane / Heating

3.1: n-BuLi / diethyl ether / 1 h / 20 °C

3.2: 56 percent / diethyl ether / -78 - 20 °C

4.1: 9-BBN / tetrahydrofuran / 5 h / 0 - 20 °C

4.2: 63 percent / Cs₂CO₃; AsPh₃; Pd(dppf)Cl₂*CH₂Cl₂ / tetrahydrofuran; dimethylformamide; H₂O / 20 - 75 °C

5.1: 94 percent / aq. K₂CO₃ / methanol

6.1: 81 percent / BF₃*OEt₂ / CHCl₃ / 48 h / 20 °C

7.1: 100 percent / CF₃SO₃H / diethyl ether / 0.33 h / 0 °C

8.1: 78 percent / dimethylsulfoxide; dimethylformamide / 72 h

With 1H-imidazole; 9-borabicyclo[3.3.1]nonane dimer; n-butyllithium; trifluorormethanesulfonic acid; boron trifluoride diethyl etherate; iodine; potassium carbonate; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; nitromethane; dichloromethane; chloroform; dimethyl sulfoxide; N,N-dimethyl-formamide;

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 685888-10-2
1-O-{11-[4-(4-methylbenzoyl)phenyl]-5-undecenyl}-2-O-(4-methoxy)benzyl-3-O-acetyl-sn-glycerol

Guidance literature:: Multi-step reaction with 6 steps

1.1: AlCl₃ / CH₂Cl₂ / 2 h / 5 - 20 °C

1.2: 61 percent / CH₂Cl₂ / 20 h / 20 °C

2.1: 9-BBN / tetrahydrofuran / 5 h / 0 - 20 °C

2.2: 63 percent / Cs₂CO₃; AsPh₃; Pd(dppf)Cl₂*CH₂Cl₂ / tetrahydrofuran; dimethylformamide; H₂O / 20 - 75 °C

3.1: 94 percent / aq. K₂CO₃ / methanol

4.1: 81 percent / BF₃*OEt₂ / CHCl₃ / 48 h / 20 °C

5.1: 100 percent / CF₃SO₃H / diethyl ether / 0.33 h / 0 °C

6.1: 78 percent / dimethylsulfoxide; dimethylformamide / 72 h

With 9-borabicyclo[3.3.1]nonane dimer; aluminium trichloride; trifluorormethanesulfonic acid; boron trifluoride diethyl etherate; potassium carbonate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform; dimethyl sulfoxide; N,N-dimethyl-formamide; 1.1: Friedel-Crafts reaction;