C₃₇H₅₀O₆Si

Base Information

Chemical Name:C₃₇H₅₀O₆Si
CAS No.:881651-71-4
Molecular Formula:C₃₇H₅₀O₆Si
Molecular Weight:618.886
Hs Code.:

C<sub>37</sub>H<sub>50</sub>O<sub>6</sub>Si

Synonyms:C₃₇H₅₀O₆Si

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Chemical Property of C₃₇H₅₀O₆Si

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Technology Process of C₃₇H₅₀O₆Si

There total 19 articles about C₃₇H₅₀O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 782479-20-3
C₄₂H₅₈O₇Si

: 881651-71-4
C₃₇H₅₀O₆Si

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; for 0.333333h;
DOI:10.1021/ja054750q

Reference yield:

: 782479-12-3
3-(2-{(R)-2-[(2R,3R,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3-triethylsilanyloxy-tetrahydro-furan-2-yl]-1-methyl-ethyl}-[1,3]dioxolan-2-yl)-propionaldehyde

: 881651-71-4
C₃₇H₅₀O₆Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: n-BuLi / toluene; tetrahydrofuran / 3 h / -30 °C

1.2: 87 percent / tetrahydrofuran; toluene / 0.5 h / -30 °C

2.1: 90 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 3 h / 0 °C

3.1: 89 percent / TMSOTf / CH₂Cl₂ / 0.17 h / -90 °C

4.1: DMSO; oxalyl dichloride; Et₃N / CH₂Cl₂ / -78 - 0 °C

5.1: n-BuLi / tetrahydrofuran; hexane / 1.33 h / -78 - 0 °C

5.2: 3.30 g / tetrahydrofuran; hexane / 2.5 h / 0 °C

6.1: 60 percent / Grubb's 2nd generation catalyst / CH₂Cl₂ / 12 h / 40 °C

7.1: 90 percent / PhI(OTf)2 / acetonitrile; various solvent(s) / 0.67 h / 0 °C / pH 7

8.1: LDA / tetrahydrofuran; hexane / -78 °C

8.2: 81 percent / N-tert-butylbenzenesulfinimidoyl chloride / tetrahydrofuran; hexane / 0.75 h / -78 °C

9.1: 80 percent / NaBH₄; CeCl₃*7H₂O / methanol / 0.67 h / -65 °C

10.1: 87 percent / pyridine; 4-DMAP / CH₂Cl₂ / 3 h / -10 °C

11.1: 82 percent / Pd₂(dba)3*CHCl₃; n-Bu₃P; LiBH₄ / 1,2-dimethoxy-ethane / 1.5 h / 0 °C

12.1: 92 percent / DIBAL-H / CH₂Cl₂ / 0.33 h / -78 °C

With pyridine; dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium tetrahydroborate; lithium borohydride; n-butyllithium; cerium(III) chloride; oxalyl dichloride; tributylphosphine; trimethylsilyl trifluoromethanesulfonate; phenyl[(trifluoromethane)sulfonyloxy]-lambda-3-iodanyl trifluoromethanesulfonate; diisobutylaluminium hydride; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; hexane; dichloromethane; toluene; acetonitrile; 4.1: Swern oxidation;
DOI:10.1021/ja054750q

Reference yield:

: 782479-15-6
C₃₆H₄₈O₆S₂Si

: 881651-71-4
C₃₇H₅₀O₆Si

Guidance literature:: Multi-step reaction with 8 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 1.33 h / -78 - 0 °C

1.2: 3.30 g / tetrahydrofuran; hexane / 2.5 h / 0 °C

2.1: 60 percent / Grubb's 2nd generation catalyst / CH₂Cl₂ / 12 h / 40 °C

3.1: 90 percent / PhI(OTf)2 / acetonitrile; various solvent(s) / 0.67 h / 0 °C / pH 7

4.1: LDA / tetrahydrofuran; hexane / -78 °C

4.2: 81 percent / N-tert-butylbenzenesulfinimidoyl chloride / tetrahydrofuran; hexane / 0.75 h / -78 °C

5.1: 80 percent / NaBH₄; CeCl₃*7H₂O / methanol / 0.67 h / -65 °C

6.1: 87 percent / pyridine; 4-DMAP / CH₂Cl₂ / 3 h / -10 °C

7.1: 82 percent / Pd₂(dba)3*CHCl₃; n-Bu₃P; LiBH₄ / 1,2-dimethoxy-ethane / 1.5 h / 0 °C

8.1: 92 percent / DIBAL-H / CH₂Cl₂ / 0.33 h / -78 °C

With pyridine; dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium tetrahydroborate; lithium borohydride; n-butyllithium; cerium(III) chloride; tributylphosphine; phenyl[(trifluoromethane)sulfonyloxy]-lambda-3-iodanyl trifluoromethanesulfonate; diisobutylaluminium hydride; lithium diisopropyl amide; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; hexane; dichloromethane; acetonitrile;
DOI:10.1021/ja054750q