Technology Process of (+/-)-Δ3,8(9)-m-menthadiene
There total 12 articles about (+/-)-Δ3,8(9)-m-menthadiene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
disodium hydrogenphosphate; sodium amalgam;
In
methanol;
for 3h;
DOI:10.1021/jo00376a009
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 33 percent / toluene / 2 h / -50 °C
2: cerium (III) chloride heptahydrate, NaBH4 / methanol / 5 h / Ambient temperature
3: 4-(dimethylamino)pyridine / CH2Cl2 / 0.5 h / Ambient temperature
4: 98 percent / n-BuLi / tetrahydrofuran; hexane / 1 h / -50 °C
5: 83.5 percent / Na2HPO4, 5percentNa-Hg / methanol / 3 h
With
dmap; sodium tetrahydroborate; disodium hydrogenphosphate; n-butyllithium; cerium(III) chloride; sodium amalgam;
In
tetrahydrofuran; methanol; hexane; dichloromethane; toluene;
DOI:10.1021/jo00376a009
- Guidance literature:
-
Multi-step reaction with 6 steps
1: p-toluenesulfonic acid monohydrate / toluene / 2 h / Heating
2: 33 percent / toluene / 2 h / -50 °C
3: cerium (III) chloride heptahydrate, NaBH4 / methanol / 5 h / Ambient temperature
4: 4-(dimethylamino)pyridine / CH2Cl2 / 0.5 h / Ambient temperature
5: 98 percent / n-BuLi / tetrahydrofuran; hexane / 1 h / -50 °C
6: 83.5 percent / Na2HPO4, 5percentNa-Hg / methanol / 3 h
With
dmap; sodium tetrahydroborate; disodium hydrogenphosphate; n-butyllithium; cerium(III) chloride; sodium amalgam; toluene-4-sulfonic acid;
In
tetrahydrofuran; methanol; hexane; dichloromethane; toluene;
DOI:10.1021/jo00376a009
![[2-(5-Methyl-cyclohex-1-enyl)-prop-2-ene-1-sulfonyl]-benzene](/Databaselist/images/loading.webp)
