(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

Base Information

Chemical Name:(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione
CAS No.:82522-07-4
Molecular Formula:C₃₅H₄₇NO₃Si
Molecular Weight:557.849
Hs Code.:

(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benz<d>isoindole-1,10-dione

Synonyms:(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

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Chemical Property of (3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

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Technology Process of (3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

There total 4 articles about (3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 82495-85-0
(2'S)-3,3-dimethyl-6-oxocyclohex-1-enyl-1-((Z,E)-N,N-benzyl-2'-<6'-(trimethylsilyl)ethoxy-4',5'-dimethyl-1'-phenyl>hexa-3',5'-dienyl)carboxamide

: 82522-07-4
(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

: 82511-63-5
3(N),4-dibenzyl-8-(2'-trimethylsilyl)ethoxy-6,7,13,13-tetramethyl-2-oxo-3-aza-9-oxatricyclo<8.4.0.0^5,10>tetradeca-1,6-diene

Guidance literature:: In toluene; at 110 ℃; for 15h;
DOI:10.1021/ja00385a029

Reference yield:

: 82495-84-9
3,3-dimethyl-6-oxocyclohex-1-ene carboxylic acid

: 82522-07-4
(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 56 percent / 2-chloro-1-methylpyridinium iodide, triethylamine / CH₂Cl₂

2: 79 percent / toluene / 15 h / 110 °C

With 2-chloro-1-methyl-pyridinium iodide; triethylamine; In dichloromethane; toluene;
DOI:10.1021/ja00385a029

Reference yield:

: 82495-82-7
(2S)-(Z,E)-N,N-benzyl-2-<6-(2'-trimethylsilyl)ethoxy-4,5-dimethyl-1-phenyl>hexa-3,5-dienylamine

: 82522-07-4
(3S,3aR,6aS,7S,10aS)-3,3a,6,6a,7,8,9,10-octahydro-2,3-dibenzyl-7-(2'-trimethylsilyl)ethoxy-4,5,7,7-tetramethyl-1H-benzisoindole-1,10-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 56 percent / 2-chloro-1-methylpyridinium iodide, triethylamine / CH₂Cl₂

2: 79 percent / toluene / 15 h / 110 °C

With 2-chloro-1-methyl-pyridinium iodide; triethylamine; In dichloromethane; toluene;
DOI:10.1021/ja00385a029