[C₆H₃(CH₂OMe)2-3,5]SnMe₃

Base Information

• Chemical Name: [C₆H₃(CH₂OMe)2-3,5]SnMe₃
• CAS No.: 1020212-47-8
• Molecular Formula: C₁₃H₂₂O₂Sn
• Molecular Weight: 329.026
• Mol file: 1020212-47-8.mol

Synonyms:[C₆H₃(CH₂OMe)2-3,5]SnMe₃

Chemical Property of [C₆H₃(CH₂OMe)2-3,5]SnMe₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [C₆H₃(CH₂OMe)2-3,5]SnMe₃

There total 1 articles about [C₆H₃(CH₂OMe)2-3,5]SnMe₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

trimethyltin(IV)chloride (1066-45-1) + 3,5-bis(methoxymethyl)iodobenzene (107146-47-4) → [C6H3(CH2OMe)2-3,5]SnMe3 (1020212-47-8)

Guidance literature:

With n-butyllithium; In diethyl ether; pentane; N2, nBuLi in pentane (19.52 mmol) added dropwise to soln. of ligand (10.27 mmol) in Et2O at -100°C with stirring, after 0.5 h soln. of Sncompd. (15.41 mmol) in Et2O added, warmed to room temp., stirred for 15 h; water added, treated with NaOH soln., org. layer treated (brine), dried (MgSO4), filtered, concd., elem. anal.;

DOI:10.1002/ejic.200600928

Reference yield: 40.0%

[C6H3(CH2OMe)2-3,5]SnMe3 (1020212-47-8) + 4'-{[(Trifluoromethyl)sulfonyl]oxy}-2,2':6',2''-terpyridine (134653-69-3) → C25H23N3O2 (1020212-48-9)

Guidance literature:

With lithium chloride; bis-triphenylphosphine-palladium(II) chloride; In toluene; for 20h; Heating;

DOI:10.1002/ejic.200600928

Reference yield:

[C6H3(CH2OMe)2-3,5]SnMe3 (1020212-47-8) → 4'-(3,5-bis(bromomethyl)phenyl)-[2,2';6',2'']terpyridine (1006610-34-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 40 percent / LiCl / [PdCl₂(PPh₃)2] / toluene / 20 h / Heating

2: 64 percent / HBr*AcOH / CH₂Cl₂ / 15 h / 20 °C

With acetic acid hydrobromide; lithium chloride; bis-triphenylphosphine-palladium(II) chloride; In dichloromethane; toluene; 1: Stille coupling;

DOI:10.1002/ejic.200600928

upstream raw materials:

trimethyltin(IV)chloride

3,5-bis(methoxymethyl)iodobenzene

Downstream raw materials:

C₂₅H₂₃N₃O₂

4'-(3,5-bis(bromomethyl)phenyl)-[2,2';6',2'']terpyridine

4'-[C₆H₃(CH₂PPh₂)2-3,5]-2,2':6',2''-terpyridine