(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

Base Information

Chemical Name:(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol
CAS No.:266682-64-8
Molecular Formula:C₂₃H₂₈O₄S
Molecular Weight:400.539
Hs Code.:

Synonyms:(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

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Chemical Property of (-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

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Technology Process of (-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

There total 1 articles about (-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-39-0
benzyl bromide

: 61819-35-0
(3aR,4R,8S,8aS)-2,2-dimethylhexahydrothiepino[4,5-d][1,3]dioxole-4,8-diol

: 266682-64-8
(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

Guidance literature:: With sodium hydride; potassium iodide; In tetrahydrofuran; for 19h;
DOI:10.1016/S0040-4020(00)00011-9

Reference yield: 87.0%

: 266682-64-8
(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

: 266682-67-1
(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol-S,S-dioxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 4h;
DOI:10.1016/S0040-4020(00)00011-9

Reference yield:

: 266682-64-8
(-)-1,6-dideoxy-2,5-di-O-benzyl-3,4-O-isopropylidene-1,6-thio-D-sorbitol

: 266682-70-6
(1S,2R,3R,4R)-(-)-1,4-di-O-benzyl-2,3-O-isopropylidenecyclohex-5-ene-1,2,3,4-tetrol

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 4 h / 20 °C

2: KOH / 2-methyl-propan-2-ol; CCl₄; H₂O / 2 h / 20 °C

With potassium hydroxide; 3-chloro-benzenecarboperoxoic acid; In tetrachloromethane; dichloromethane; water; tert-butyl alcohol; 1: Oxidation / 2: Ramberg-Baecklung reaction;
DOI:10.1016/S0040-4020(00)00011-9