(C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BLi

Base Information

• Chemical Name: (C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BLi
• CAS No.: 956014-22-5
• Molecular Formula: C₂₆H₃₈BLiN₂
• Molecular Weight: 396.353
• Mol file: 956014-22-5.mol

Synonyms:(C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BLi

Chemical Property of (C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BLi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BLi

There total 5 articles about (C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BLi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-bromo-1,3-bis[2,6-di-(propan-2-yl)phenyl]-1,3,2-diazaborolidine (956014-21-4) → (C2H4N2(2,6-(iPr)2C6H3)2)BLi (956014-22-5)

Guidance literature:

With naphthalene; lithium; In tetrahydrofuran-d8; at -45 ℃; for 35h;

DOI:10.1002/anie.200702369

Reference yield:

2-bromo-1,3-bis[2,6-di-(propan-2-yl)phenyl]-1,3,2-diazaborolidine (956014-21-4) + lithium (7439-93-2) → (C2H4N2(2,6-(iPr)2C6H3)2)BLi (956014-22-5)

Guidance literature:

With catalyst: naphthalene; In tetrahydrofuran-d8; byproducts: LiBr; treatment of boron compd. with lithium in THF-d8 in presence of naphthalene at -45°C for 35 h; detected by NMR;

DOI:10.1021/ja8057919

Reference yield:

N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine (134030-22-1) → (C2H4N2(2,6-(iPr)2C6H3)2)BLi (956014-22-5)

Guidance literature:

Multi-step reaction with 2 steps

1: N(CH₂CH₃)3 / not given

2: catalyst: naphthalene / tetrahydrofuran-d8

With N(CH₂CH₃)3; catalyst: naphthalene; In tetrahydrofuran-d8;

DOI:10.1021/ja8057919

upstream raw materials:

2-bromo-1,3-bis[2,6-di-(propan-2-yl)phenyl]-1,3,2-diazaborolidine

lithium

N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine

Downstream raw materials:

(C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BH

(C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BOH

(C₂H₄N₂(2,6-(iPr)2C₆H₃)2)BCOPh