bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper

Base Information

Chemical Name:bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper
CAS No.:635680-64-7
Molecular Formula:C₁₆H₃₄Cu₂N₄
Molecular Weight:409.565
Hs Code.:

Synonyms:copper(I) N,N'-di-isopropylacetamidinate

Suppliers and Price of bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper

Chemical Property:

Melting Point:152-154?°C(lit.)
Boiling Point:70?°C/0.05?mmHg

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper

There total 4 articles about bis[μ-[n,n'-bis(1-methylethyl)-ethanimidamidato-κn:κn']]di-copper which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 106500-93-0
N,N'-bis(isopropyl)ethanimidamide

: copper(l) chloride

: 635680-64-7
copper(I) N,N'-di-isopropylacetamidinate

Guidance literature:: With methyllithium; In diethyl ether; under N2 atm. soln. MeLi in Et2O was added at -30°C to soln. amidine in Et2O, stirred for 2 h at room temp. and added to CuCl in Et2O, stirred for 18 h; solvent was removed in vacuo, residue was extd. with hexane, filtered, concd. in vacuo, and cooled to -30°C; elem. anal.;
DOI:10.1021/ic048492u

Reference yield: 70.0%

: 917-54-4
methyllithium

: 7787-70-4
copper(I) bromide

: 693-13-0
diisopropyl-carbodiimide

: 635680-64-7
copper(I) N,N'-di-isopropylacetamidinate

Guidance literature:: In diethyl ether; under N2 atm. soln. MeLi in Et2O was added dropwise to soln. 1,3-diisopropylcabodiimide in Et2O at -30°C, react. mixt. was warmed to roomtemp., stirred for 4 h, added to soln. CuBr in Et2O and stirred for 12 h under exclusion of light; volatiles were removed under reduced pressure, residue was extd. with hexane, filtered through Celite, concd. and cooled to -30°C, sublimation; elem. anal.;
DOI:10.1021/ic0345424

Reference yield:

: 693-13-0
diisopropyl-carbodiimide

: 635680-64-7
copper(I) N,N'-di-isopropylacetamidinate

Guidance literature:: Multi-step reaction with 2 steps

1: Schlenk technique; Inert atmosphere

2: Schlenk technique; Inert atmosphere

DOI:10.1002/open.201600105