prop-2-ene-1,1-diyl dibenzoate

Base Information

• Chemical Name: prop-2-ene-1,1-diyl dibenzoate
• CAS No.: 1208092-25-4
• Molecular Formula: C₁₇H₁₄O₄
• Molecular Weight: 282.296
• Mol file: 1208092-25-4.mol

Synonyms:prop-2-ene-1,1-diyl dibenzoate

Chemical Property of prop-2-ene-1,1-diyl dibenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of prop-2-ene-1,1-diyl dibenzoate

There total 1 articles about prop-2-ene-1,1-diyl dibenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

benzoic acid anhydride (93-97-0) + acrolein (107-02-8,25068-14-8) → prop-2-ene-1,1-diyl dibenzoate (1208092-25-4)

Guidance literature:

With sulfuric acid; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1021/ja9097675

Reference yield: 47.0%

prop-2-ene-1,1-diyl dibenzoate (1208092-25-4) + hexanal (66-25-1) → (3R,4S)-3-benzoyloxynon-1-en-4-ol (1449522-82-0)

Guidance literature:

With potassium phosphate; [(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole][4-cyano-3-nitrobenzenecarboxylato] [1,2,3-eta-2-propenyl Ir(III)]; In tetrahydrofuran; isopropyl alcohol; at 60 ℃; for 52h; enantioselective reaction; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.07.038

Reference yield:

santene (529-16-8) + prop-2-ene-1,1-diyl dibenzoate (1208092-25-4) → (E)-3-((1SR,2RS,4RS)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)prop-1-en-1-yl benzoate + (E)-3-((1SR,2SR,4RS)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)prop-1-en-1-yl benzoate

Guidance literature:

With zinc(II) iodide; In dichloromethane; at 20 ℃; Overall yield = 39 %; Overall yield = 110 mg;

upstream raw materials:

benzoic acid anhydride

acrolein

Downstream raw materials:

(3S,3R,E)-1-phenylhexa-1,5-diene-3,4-diol

(3S,3R,E)-1-phenylhexa-1,5-diene-3,4-diyl dibenzoate

(3R,4S)-dodec-1-ene-3,4-diyl dibenzoate

(1S,2R)-1-(6-bromopyridin-2-yl)but-3-ene-1,2-diyl dibenzoate